Titanium Catalyst Turns Racemic Lactide into Heterotactic Polylactide and Tapered Lactide-Caprolactone Copolymers
A cyclopentadienyl-silsesquioxane titanium complex polymerizes rac-lactide into heterotactic-enriched polylactide and produces tapered lactide-caprolactone copolymers, with DFT calculations explaining the stereochemical ...
