Tropical Estuary Sediments Reassuringly Low in Uranium and Thorium, Study Finds

Estuaries are among the most dynamic geochemical environments on Earth, places where rivers release their sediment loads into the sea and where fine-grained particles accumulate over decades, quietly recording the geological and human history of an entire catchment. Because naturally occurring radionuclides such as potassium-40, uranium-238 and thorium-232 bind readily to these sediments, estuarine deposits can act as long-term reservoirs of radioactivity and, in some settings, as sources of chronic external radiation exposure to people who fish, farm, swim or build along the water’s edge. A new study published in the journal Environmental Monitoring and Assessment has now provided one of the most detailed baseline pictures of this phenomenon for a tropical river system, and its central message is unexpectedly reassuring: despite the presence of both natural geological processes and human activity in the catchment, the radiological burden carried by the estuary’s sediments falls comfortably within internationally accepted safety limits.

The research, conducted by Blessing N. Ben-Festus and Festus Ben of the Centre for Advanced Materials Research and Development at Federal Polytechnic Ede in Nigeria, with Ben also affiliated with the Centre for Nanoengineering and Advanced Materials at the University of Johannesburg, focused on sediments within a tropical river estuarine system in southwestern Nigeria. The fieldwork was carried out in a waterway shaped by seasonal rainfall and runoff, artisanal and urban pressures, and the steady downstream delivery of weathered material from the surrounding landscape. Regions of this kind are often underrepresented in global radiological databases, which historically have emphasized temperate environments, making the new dataset a valuable reference point not only for Nigeria but for comparative assessments of depositional environments worldwide.

Technically, the study relied on gamma-ray spectrometry, the workhorse technique of environmental radiochemistry. Sediment samples collected from the estuary were prepared, sealed to allow radioactive equilibrium to be established, and then quantified using a calibrated sodium iodide detector, a scintillation-based instrument that records the characteristic gamma-ray energies emitted by decaying nuclides. Sodium iodide spectrometers are prized in field-adjacent laboratories for their high detection efficiency and relatively low cost, although they demand careful energy and efficiency calibration to resolve the photopeaks of interest. The authors followed established calibration practice, drawing on the well-documented performance characteristics of 3-inch by 3-inch NaI(Tl) detectors, to convert counts into activity concentrations expressed in becquerels per kilogram, a unit that describes the number of radioactive decays per second in each kilogram of dry sediment.

The measured activity concentrations told a consistent story. Potassium-40, the primordial isotope that has persisted since the formation of the Earth and pervades virtually all crustal material, averaged 490.50 plus or minus 7.66 becquerels per kilogram across the samples. Uranium-238, the head of the uranium decay series, averaged just 5.67 plus or minus 0.20 becquerels per kilogram, and thorium-232, the progenitor of the thorium series, registered 4.81 plus or minus 0.26 becquerels per kilogram. Benchmarked against the reference values published by the United Nations Scientific Committee on the Effects of Atomic Radiation, the potassium result ran about 16.79 percent above the global average, a modest elevation the authors attribute to the potassium-rich minerals weathered from the catchment’s bedrock and soils. By contrast, the uranium and thorium figures sat far below the corresponding global thresholds, at 82.82 percent and 89.31 percent below them, respectively, underscoring how strongly the local geology, rather than industrial contamination, controls the radiological signature of these deposits.

Raw concentrations, however, are only the starting point of a radiological risk assessment. Because potassium-40, uranium-238 and thorium-232 differ in the energy and intensity of the gamma radiation they emit, regulators and researchers combine them into derived indices that better approximate real-world exposure. The study calculated the radium equivalent activity, a composite quantity that weights the three nuclides according to their relative gamma dose contributions, and obtained a mean value of 50.32 becquerels per kilogram, well under the widely cited 370 becquerels per kilogram ceiling that marks the threshold above which structural or land-use restrictions might be considered. This single number already suggests that neither beachcombers nor construction workers handling dredged sediment would encounter unusual radiation fields at the site.

The dose-based indicators reinforce that conclusion. The absorbed gamma dose rate in air at one meter above the sediment surface averaged 26.13 nanogray per hour, translating into an annual effective dose of roughly 0.03 millisievert per year for a member of the public spending typical time near or on the sediments. For context, the global average outdoor terrestrial dose attributable to natural radionuclides is generally estimated at around 0.07 millisievert per year, meaning the Nigerian estuary delivers less than half of that conventional background. The team also evaluated the annual gonadal dose, a quantity used to approximate the genetically significant dose to reproductive organs, obtaining 191.64 microsieverts per year, again comfortably below the internationally recognized screening level of about 300 microsieverts per year. Taken together, these parameters indicate that external exposure pathways linked to the estuary’s sediments pose no significant radiological risk to the surrounding communities.

The findings matter for reasons that extend beyond a single river. Sediments are the memory of a river system: they trap not only radionuclides but also heavy metals, nutrients and pollutants, and their radioactive inventory reflects the interplay of bedrock composition, weathering intensity, grain-size sorting and hydrodynamic energy. In tropical climates, intense rainfall and episodic flooding periodically resuspend and redistribute these deposits, meaning that a baseline established today is the essential yardstick against which future disturbance, whether from mining, dredging, dam construction or land-use change, can be judged. Comparable investigations along the Arvand River in Iran, the Pashur River in Bangladesh, the Ravi River in Pakistan and the coastal wetlands of southern Taiwan have revealed that fluvial radioactivity can vary enormously with geology, and in some industrialized estuaries technogenic nuclides from mining discharges or phosphogypsum releases dominate the picture. Against that backdrop, the low uranium and thorium readings in this Nigerian system signal an environment whose radiological profile remains essentially natural.

The study also contributes methodological value to the radiological sciences. Gamma spectrometry with sodium iodide detectors requires meticulous attention to detection efficiency, coincidence summing effects and source-to-detector geometry, and the growing literature on detector calibration offers practical guidance for laboratories working with modest infrastructure. By demonstrating that credible, standards-aligned hazard assessments can be produced with such instrumentation, the research lowers the barrier for similar monitoring programs in other data-poor tropical basins. The authors acknowledge research assistants Miss Daud Ajarat Olaide and Mr. Adeyeni Tunmise Afolabi for their contributions during the field study, and the work was funded by the Centre for Advanced Materials Research and Development, highlighting the role of institutionally supported, locally grounded science in filling global environmental data gaps.

Looking ahead, the researchers position their dataset as a foundation for longitudinal monitoring. Natural radioactivity is not static: sediments are eroded, redeposited and chemically transformed, and the same estuary measured after a decade of accelerated development could present a different signature. The measured values, now archived in the peer-reviewed literature and available upon reasonable request, give regulators in Osun State and beyond a defensible pre-disturbance benchmark. They also give residents a rare piece of quantified good news: the muds beneath their river, far from being a hidden radiological hazard, are among the quieter sediments on the planet, holding only a whisper of the uranium and thorium that Earth’s crust normally carries, and a dose burden that any international safety authority would judge unremarkable.

Subject of Research: Measurement of natural radionuclide activity concentrations and radiological hazard indices in sediments of a tropical river estuarine system

Article Title: Sediment-associated natural radionuclide and radiological risk indicators in a tropical river estuarine system

Article References: Ben-Festus, B. N., & Ben, F. (2026). Sediment-associated natural radionuclide and radiological risk indicators in a tropical river estuarine system. Environmental Monitoring and Assessment, 198(10), Article 1069. https://doi.org/10.1007/s10661-026-15895-w

Image Credits: AI Generated

DOI: 10.1007/s10661-026-15895-w

Keywords: natural radionuclides, gamma spectrometry, estuarine sediments, radiological risk, potassium-40, uranium-238, thorium-232, tropical river, environmental monitoring, radiation dose, Nigeria, radium equivalent activity