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Impact of Gamma Rays on Recombination Dynamics and Defect Levels in Wide Bandgap Perovskites

January 21, 2025
in Space
Reading Time: 4 mins read
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Figure 1 | Mobile ion concentration Ni (black) and Diffusion coefficient D0 (blue) as a function of absorbed dose.
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In the ever-evolving landscape of material science, perovskite solar cells have emerged as a beacon of promise, especially due to their unique properties and adaptability to varying environmental conditions. Recent studies have taken a bold step forward in understanding the robustness of these materials, particularly in the context of space applications where radiation exposure poses significant challenges. Researchers have increasingly recognized that complex lead halides, which exhibit perovskite structures, are surprisingly resistant to high-energy radiation, making them indispensable in fields that demand high-performance materials under extreme conditions. This resistance to radiation, highlighted in various studies, positions perovskite semiconductors as prime candidates for solar cells aimed at space missions as well as X-ray and gamma-ray detection technologies.

The effects of high-energy radiation, such as gamma rays from isotopes like cobalt-60 and cesium-137, have been a focal point for scientists aiming to assess the radiation hardness of perovskite materials. The operational environment of space—characterized by an oxygen and moisture vacuum—promises longevity for perovskite solar cells, which underscores their potential for long-term use in orbital stations and spacecraft. However, the challenge persists regarding the impact of total ionizing dose (TID) on these materials, as accumulated doses can range significantly, affecting performance over time. It is critical for researchers to establish a reliable understanding of how these materials behave under prolonged doses of radiation, paving the way for advancements in space-based energy systems.

In a recent publication in the prestigious journal, "Light: Science & Application," a research group led by Dr. Aleksandra Boldyreva from the Skolkovo Institute of Science and Technology took a significant leap in assessing the gamma-ray stability of a wide bandgap perovskite, which has a bandgap of 1.75 eV. This particular study revealed key insights into how small doses of gamma radiation, up to 10 kGy, can lead to passivation of certain negatively charged defects within perovskite films while simultaneously activating other intrinsic defects. Notably, admittance spectroscopy played a pivotal role, revealing that defects with an energy level of approximately 0.5 eV in the perovskite films demonstrated a remarkable decrease in concentration with increased gamma radiation exposure.

Furthermore, the diffusion coefficient—a measure of how quickly defects move within the material—increased significantly, by two orders of magnitude, after exposure to 6 kGy of radiation. This behavior is anomalous compared to typical Schottky-type defects, which usually see an increase in diffusion with an increase in their concentration. The peculiarity of this observation highlights the unique interactions between gamma radiation and the structural integrity of perovskite materials, indicating a complex mechanism at play that warrants deeper investigation.

As further gamma-ray doses were accumulated, the study observed a saturation effect in both the defect concentration and the diffusion coefficient. This surprising trend hints at intricate interactions between radiation and the defect dynamics within perovskite structures. Specifically, interactions at photon energies of 662 keV enforce the photoelectric effect, wherein electrons become excited by gamma photons, leading to vacancies or unrecombined holes left behind. As the presence of interfacial defects becomes prominent, gamma interactions result in a reduction of non-radiative recombination, a critical aspect for optimizing the efficiency of solar cells.

The study elucidates that an elevation in newly formed defects, as a byproduct of gamma exposure, leads to a tipping point where further radiation results in material degradation and a shift towards non-radiative recombination. This balance between defect passivation and introduction of new defects is central to developing robust perovskite materials capable of withstanding the rigors of space environments. The nuanced understanding of defect dynamics not only adds layers to the existing body of knowledge but also reshapes directions for future research focused on materials for space applications.

To better visualize the effect of gamma radiation, the researchers conducted analyses on fresh and exposed perovskite solar cells using annular dark-field scanning transmission electron microscopy (HAADF-STEM). The findings indicated a significant difference in iodine distribution between the exposed and unexposed samples, suggesting that radiation exposure can alter the elemental makeup and possibly the electronic properties of the perovskite structure.

The dominant defects identified were iodine vacancies, denoted as V, which saw a marked decrease in concentration with exposure to gamma rays. The research highlighted that this reduction aligns with the observed increase in the diffusion coefficient, pointing towards a migration mechanism through freshly created defects. This understanding is crucial, especially for the design of new perovskite compositions that could enhance performance while promoting stability under radiation conditions akin to space.

In summary, the findings from this recent study are indicative of a burgeoning field poised to revolutionize solar energy applications, not only on Earth but also in extraterrestrial realms. The exploration of defect dynamics under gamma radiation sets the stage for innovative solutions to improve the operational lifespan and efficiency of perovskite solar cells subjected to harsh conditions. As scientists continue to unravel the complexities of these unique materials, the insights garnered highlight the potential for perovskites to not only meet but exceed the demands of modern energy solutions.

The implications of this research extend beyond theoretical knowledge, as industrial applications geared towards space exploration and high-energy environments necessitate durable materials capable of sustaining performance in the face of adversity. As the demand for reliable energy sources in space grows, scientists are optimistic that the advancements made in understanding the behavior of perovskite materials under radiation will facilitate the design of next-generation solar cells and detectors, propelling humanity’s journey into the cosmos.

This continuous quest for knowledge and the development of robust materials symbolizes a pivotal shift in material science, nurturing a future where energy systems are as reliable as they are innovative. Perovskites exemplify the fusion of nature’s design with human ingenuity, setting a poignant example of how scientific exploration can lead to sustainable solutions for tomorrow.

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Subject of Research: Gamma Ray Stability of Wide Bandgap Perovskites
Article Title: Effect of gamma-rays on recombination dynamics and defect concentration in a wide bandgap perovskite
News Publication Date: October 2023
Web References: Link to Article
References: Light: Advanced Manufacturing
Image Credits: Aleksandra G. Boldyreva et al.

Keywords

Perovskite Solar Cells, Gamma Radiation, Defect Dynamics, Space Applications, Radiation Hardness, Energy Efficiency

Tags: Defect DynamicsDefect PassivationGamma RadiationIonizing Dose EffectsMaterial DegradationPerovskite Solar CellsRadiation HardnessRadiation-Induced DefectsRecombination DynamicsSemiconductor StabilitySpace ApplicationsWide Bandgap Perovskites
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