Scientists at the Helmholtz-Zentrum Dresden-Rossendorf (HZDR) together with colleagues from the Helmholtz-Zentrum Berlin (HZB) and the University of Virginia in Charlottesville, USA have found a way to write and delete magnets in an alloy using a laser beam – a surprising effect. The reversibility of the process opens up new possibilities in the fields of material processing, optical technology, and data storage.
Researchers of the HZDR, an independent German research laboratory, studied an alloy of iron and aluminum. It is interesting as a prototype material because subtle changes to its atomic arrangement can completely transform its magnetic behavior. "The alloy possesses a highly ordered structure, with layers of iron atoms that are separated by aluminum atomic layers. When a laser beam destroys this order, the iron atoms are brought closer together and begin to behave like magnets," says HZDR physicist Rantej Bali.
Bali and his team prepared a thin film of the alloy on top of transparent magnesia through which a laser beam was shone on the film. When they, together with researchers of the HZB, directed a well-focused laser beam with a pulse of 100 femtoseconds (a femtosecond is a millionth of a billionth of a second) at the alloy, a ferromagnetic area was formed. Shooting laser pulses at the same area again – this time at reduced laser intensity – was then used to delete the magnet.
With a single laser pulse at reduced intensity, about half of the previous level of magnetization was retained, and with a series of laser pulses, the magnetization disappeared altogether. These observations were made at the HZB-run Bessy II synchrotron using a microscope that deploys soft X-rays to study the magnetic contrast.
Working with a team from the University of Virginia in Charlottesville, USA the scientist were able to clarify what happens in the alloy during this process. The simulations of the American colleagues show that the ferromagnetic state is formed when the ultra-short laser pulse heats up the thin-film material to the extent that it melts, all the way from the surface to the magnesia interface. As the alloy cools down it enters a state known as a "supercooled liquid" wherein it remains molten, despite the temperature having dropped below the melting point. This state is reached because of a lack of nucleation sites – microscopic locations where the atoms can begin to arrange into a lattice. As the atoms move around in the supercooled state in search for nucleation sites, the temperature continues to drop. Finally, the atoms in the supercooled state must form a solid lattice, and like in a game of musical chairs, the iron and aluminum atoms end up being trapped in random positions within the lattice. The process takes only a few nanoseconds and the random arrangement of atoms renders a magnet.
The same laser, but with a reduced intensity, rearranges the atoms into a well ordered structure. The weaker laser shot melts only thin layers of the film, creating a molten pool sitting on the solid alloy. Within a nanosecond after melting, and as soon as the temperature drops below the melting point, the solid part of the film starts to regrow, and the atoms rapidly rearrange from the disordered liquid structure to the crystal lattice. With the lattice already formed and the temperature still being high enough, the atoms possess sufficient energy to diffuse through the lattice and separate into layers of iron and aluminum. PhD student Jonathan Ehrler summarizes: "To write magnetic areas, we have to melt the material from the surface down to the interface, while to delete it, we only need to melt a fraction of it."
In further experiments, the scientists now want to investigate this process in other ordered alloys. They also want to explore the impact of a combination of several laser beams. Interference effects could be used to generate patterned magnetic materials over large areas. "The remarkably strong changes to the material property may well lead to some interesting applications," reckons Bali. Lasers are used for many different purposes in industry, for instance in material processing. This discovery may also open further avenues in optical and data storage technologies.
Publication: Jonathan Ehrler et al., ACS Applied Materials & Interfaces, "Laser-rewriteable Ferromagnetism at Thin Film Surfaces", DOI: http://dx.doi.org/10.1021/acsami.8b01190
Dr. Rantej Bali / Jonathan Ehrler
Institute of Ion Beam Physics and Materials Research at HZDR
Phone +49 351 260 – 2919
Email: [email protected] / [email protected]