<?xml version="1.0" encoding="UTF-8"?><rss version="2.0"
	xmlns:content="http://purl.org/rss/1.0/modules/content/"
	xmlns:wfw="http://wellformedweb.org/CommentAPI/"
	xmlns:dc="http://purl.org/dc/elements/1.1/"
	xmlns:atom="http://www.w3.org/2005/Atom"
	xmlns:sy="http://purl.org/rss/1.0/modules/syndication/"
	xmlns:slash="http://purl.org/rss/1.0/modules/slash/"
	>

<channel>
	<title>Mullins effect &#8211; Science</title>
	<atom:link href="https://scienmag.com/tag/mullins-effect/feed/" rel="self" type="application/rss+xml" />
	<link>https://scienmag.com</link>
	<description></description>
	<lastBuildDate>Fri, 09 Oct 2026 04:56:11 +0000</lastBuildDate>
	<language>en-US</language>
	<sy:updatePeriod>
	hourly	</sy:updatePeriod>
	<sy:updateFrequency>
	1	</sy:updateFrequency>
	<generator>https://wordpress.org/?v=7.1.3</generator>

<image>
	<url>https://scienmag.com/wp-content/uploads/2024/07/cropped-scienmag_ico-32x32.jpg</url>
	<title>Mullins effect &#8211; Science</title>
	<link>https://scienmag.com</link>
	<width>32</width>
	<height>32</height>
</image> 
<site xmlns="com-wordpress:feed-additions:1">73899611</site>	<item>
		<title>How Fatigue Cracks Eat Wind Turbine Blades: A New Fracture Mechanics Test Could Transform Erosion Protection</title>
		<link>https://scienmag.com/how-fatigue-cracks-eat-wind-turbine-blades-a-new-fracture-mechanics-test-could-transform-erosion-protection/</link>
		
		<dc:creator><![CDATA[Faith Mcneil]]></dc:creator>
		<pubDate>Fri, 09 Oct 2026 04:56:11 +0000</pubDate>
				<category><![CDATA[Climate]]></category>
		<category><![CDATA[Technology and Engineering]]></category>
		<category><![CDATA[cyclic loading effects on wind turbine blade materials]]></category>
		<category><![CDATA[elastomers]]></category>
		<category><![CDATA[fatigue crack growth]]></category>
		<category><![CDATA[fatigue crack initiation in protective coatings]]></category>
		<category><![CDATA[fracture mechanics]]></category>
		<category><![CDATA[fracture mechanics of wind turbine blade coatings]]></category>
		<category><![CDATA[innovative methods for wind turbine blade protection]]></category>
		<category><![CDATA[leading-edge damage in wind turbines]]></category>
		<category><![CDATA[leading-edge erosion]]></category>
		<category><![CDATA[material degradation due to rain impact]]></category>
		<category><![CDATA[materials testing]]></category>
		<category><![CDATA[micro-impact stress waves on wind turbine blades]]></category>
		<category><![CDATA[Mullins effect]]></category>
		<category><![CDATA[new testing approaches for wind turbine erosion resistance]]></category>
		<category><![CDATA[polyurethane]]></category>
		<category><![CDATA[rain erosion]]></category>
		<category><![CDATA[rain erosion testing for wind turbine materials]]></category>
		<category><![CDATA[tearing energy]]></category>
		<category><![CDATA[visco-elasticity]]></category>
		<category><![CDATA[wind energy]]></category>
		<category><![CDATA[wind energy blade repair and maintenance]]></category>
		<category><![CDATA[wind turbine blade erosion]]></category>
		<category><![CDATA[wind turbine blades]]></category>
		<category><![CDATA[X-ray computed tomography for erosion analysis]]></category>
		<guid isPermaLink="false">https://scienmag.com/?p=251893</guid>

					<description><![CDATA[Danish researchers have developed a fracture mechanics test showing that tearing energy, not strain, governs fatigue crack growth in the elastomers protecting wind turbine blades from rain erosion, revealing a sharp threshold that could transform material design and turbine operation.]]></description>
										<content:encoded><![CDATA[<p>Every time a raindrop strikes the leading edge of a spinning wind turbine blade, it delivers a microscopic hammer blow. At tip speeds approaching several hundred kilometers per hour, water droplets behave less like liquid and more like high-velocity projectiles, generating transient stress waves that race through the protective polymer coating in microseconds. Over millions of such impacts, the material at the blade&#8217;s leading edge begins to disintegrate, a phenomenon known as leading-edge erosion that costs the wind industry dearly in lost energy production and repairs. Now, researchers at the Technical University of Denmark have introduced a fundamentally new way of understanding and measuring this damage, one that could reshape how protective materials are designed, tested, and certified.</p>
<p>Jakob Ilsted Bech and Jamie Engelhardt Simon, writing in the journal Wind Energy Science, argue that the dominant failure mode in modern leading-edge protection systems is not the gradual, uniform wearing-away that conventional models assume, but rather fatigue cracking: the initiation and growth of discrete cracks driven by the cyclic pulse loading of successive droplet impacts. Their X-ray computed tomography images of rain-eroded samples reveal locally occurring cracks surrounded by virtually undamaged material, a signature that looks far more like classical fatigue fracture than like progressive surface loss. For soft, tough, visco-elastic elastomers, the polyurethanes and similar polymers increasingly used to shield blade tips, this distinction matters enormously, because the old stress-based damage models simply do not capture how these materials fail.</p>
<p>The physics of a droplet impact is violent and fast. Numerical studies predict local strains of up to 80 percent and strain rates between 1,000 and 1,000,000 per second during the microseconds of contact. The resulting stress patterns depend on impact velocity, droplet size, and the hyper-visco-elastic properties of the surface. Classic experiments dating back to Bowden and Brunton in 1961 showed that a single high-speed water jet can fracture a polymer, and the crack patterns differ by material type: hard elastic polymers develop ring-shaped surface cracks that propagate conically into the depth, while soft rubbers nucleate cracks inside the bulk, beneath the impact center, which then spread in star-shaped patterns. On a real blade, where droplets strike at random positions, cracks may initiate at randomly distributed defects and inhomogeneities, making the damage harder to predict but no less governed by the laws of fracture mechanics.</p>
<p>Bech and Simon&#8217;s central contribution is to bring the established tools of experimental fracture mechanics to bear on this problem for the first time. The key quantity is the tearing energy, T, the energy per unit area released as a crack advances, a concept that traces back to Rivlin and Thomas&#8217;s foundational 1953 work on rubber rupture. To measure it, the researchers employed a plane strain tensile test with two slits, often called the pure shear test, in which a thin polymer sheet is clamped at its edges and pre-cut cracks grow under cyclic loading. Because the geometry produces a uniform plane-strain zone between the crack tips and a stress-free zone behind them, the tearing energy can be computed from a remarkably simple energy balance. Their novel analysis technique tracks the evolution of strain energy with crack length throughout the test, comparing the work required to stretch the specimen at successive cycle intervals, so that the energy released per unit of new crack area emerges directly from the measured load-displacement loops.</p>
<p>Testing soft elastomer sheets posed its own engineering challenge. Rubber-like materials are notoriously difficult to grip because they contract in the thickness direction under tension and slip out of conventional flat-jaw grips. The team designed a new test fixture with partially circular grip faces, a 90-degree concave cylinder that wraps around the specimen and compresses it progressively, maintaining grip even at high strains. A prototype was 3D printed in PLA plastic and mounted in an electro-pulse test machine, with specimens cut from sheet material into rectangles of 80 by 46 millimeters. A digital camera recorded the crack tips at peak displacement throughout each test, allowing crack lengths to be tracked by image analysis with a resolution of about 0.02 millimeters per pixel.</p>
<p>Crucially, the loading scheme was designed to mimic the rhythm of rain. Each cycle consists of a short sinusoidal displacement pulse followed by a dwell time before the next pulse, representing the interval between successive droplet impacts. Two dwell times were tested, 0.1 and 1 second, chosen from computed impact frequencies for realistic rain fields, although the researchers note that characteristic impact periods in the field can range from 1 to 100 seconds. This dwell-time dependence turned out to be one of the most revealing aspects of the study, because the material exhibits pronounced visco-elastic behavior, including the Mullins effect, a cyclic stress softening in which stiffness and energy uptake decline over repeated cycles before stabilizing.</p>
<p>The softening behavior was dramatic. With a dwell time of 0.1 seconds, the maximum load in an uncracked specimen fell from about 221 newtons in the first cycle to 126 newtons by cycle 2,000, and the strain energy dropped from 0.28 to 0.15 joules. After a 10-minute recovery period, the same specimen tested with a 1-second dwell time nearly regained its initial state, reaching 215 newtons and 0.27 joules before softening again to 171 newtons and 0.22 joules. With a 10-second dwell time, the material almost fully recovered between cycles, ending at 211 newtons and 0.27 joules after 2,000 cycles. Shorter dwell times also required more cycles to reach stable, repeatable stress-strain loops, meaning that any meaningful crack growth measurement demands a run-in period of potentially several hundred cycles before the material settles into a steady state.</p>
<p>When the crack growth rate per cycle was plotted against maximum strain, the results appeared dwell-time dependent: cracks grew faster at the longer 1-second dwell time, and the strain threshold between slow and fast growth differed by roughly 27 percent between the two regimes. Longer dwell times allow greater recovery between pulses, so the material resumes each cycle at higher stiffness and can absorb more strain energy for a given peak strain, delivering a larger tearing energy to the crack tip. But here lies the study&#8217;s most elegant finding: when the same data were plotted against tearing energy rather than strain, the curves for both dwell times collapsed onto a single master curve, differing by only about 10 percent in threshold. Above the threshold, the data follow a power law relating growth rate to tearing energy with an exponent of about 2.2. Tearing energy, not strain, is the governing parameter, independent of how fast the impacts arrive, at least for the dwell times tested.</p>
<p>The measured crack growth rates spanned a striking range. Below a tearing energy threshold estimated at approximately 2,100 joules per square meter, with a standard deviation of about 200, cracks grew at only 3 to 6 nanometers per cycle, effectively negligible. Above the threshold, rates jumped to between 0.6 and 10 micrometers per cycle, three orders of magnitude faster. Some tests revealed intriguing anomalies: one crack sat dormant for nearly 570,000 cycles before abruptly accelerating, suggesting the threshold had been marginally crossed; another crack paused at an apparent tough inhomogeneity before finding a path around it and resuming its original rate. These observations reinforce the picture of a sharp fatigue limit, analogous to the mechanical fatigue limit long established for rubber, below which a component could theoretically endure impacts indefinitely.</p>
<p>The implications reach well beyond the laboratory. The authors propose that crack growth resistance could become a key parameter in material standards, in the systematic development of new protective coatings, and even in operational strategy. In so-called erosion-safe operation, the tearing energy threshold could serve as a curtailment criterion, with rotor speed limited during extreme precipitation so that the energy delivered to cracks stays below the propagation threshold, a function of protection material properties and meteorological conditions such as droplet size and liquid water content. The fracture mechanics approach also offers a mechanistic basis for evaluating materials before costly whirling-arm rain erosion testing, and the authors call for future work on ultra-high strain rates, possibly using low temperatures and time-temperature superposition to mimic impact conditions, and on rain erosion tests with controlled defects to link laboratory fracture data directly to field performance. If successful, this paradigm shift could finally give the wind industry a rigorous, physics-based route to eliminating one of its most persistent and expensive failure modes.</p>
<p><strong>Subject of Research:</strong> Fatigue crack growth characterization of elastomeric leading-edge protection materials for wind turbine blades using experimental fracture mechanics</p>
<p><strong>Article Title:</strong> Fatigue crack growth in elastomers for leading-edge erosion protection of wind turbine blades</p>
<p><strong>Article References:</strong> Bech, J. I., &amp; Simon, J. E. (2026). Fatigue crack growth in elastomers for leading-edge erosion protection of wind turbine blades. <em>Wind Energy Science, 11</em>(10), 3803-3821. <a href="https://doi.org/10.5194/wes-11-3803-2026" rel="noopener noreferrer">https://doi.org/10.5194/wes-11-3803-2026</a></p>
<p><strong>Image Credits:</strong> AI Generated</p>
<p><strong>DOI:</strong> <a href="https://doi.org/10.5194/wes-11-3803-2026" rel="noopener noreferrer">10.5194/wes-11-3803-2026</a></p>
<p><strong>Keywords:</strong> wind energy, leading-edge erosion, fatigue crack growth, elastomers, fracture mechanics, tearing energy, polyurethane, rain erosion, Mullins effect, wind turbine blades, materials testing, visco-elasticity</p>
]]></content:encoded>
					
		
		
		<post-id xmlns="com-wordpress:feed-additions:1">251893</post-id>	</item>
		<item>
		<title>Rubber That Creeps Under Pressure: Scientists Decode the Ratcheting Secrets of Nitrile Rubber</title>
		<link>https://scienmag.com/rubber-that-creeps-under-pressure-scientists-decode-the-ratcheting-secrets-of-nitrile-rubber/</link>
		
		<dc:creator><![CDATA[Bethany Barker]]></dc:creator>
		<pubDate>Sun, 04 Oct 2026 06:08:08 +0000</pubDate>
				<category><![CDATA[Chemistry]]></category>
		<category><![CDATA[constitutive modeling]]></category>
		<category><![CDATA[cumulative strain in nitrile rubber]]></category>
		<category><![CDATA[cyclic loading]]></category>
		<category><![CDATA[cyclic stress analysis in polymers]]></category>
		<category><![CDATA[deformation correction parameter]]></category>
		<category><![CDATA[elastomers]]></category>
		<category><![CDATA[engineering applications of nitrile rubber under cyclic loads]]></category>
		<category><![CDATA[failure mechanisms in rubber components]]></category>
		<category><![CDATA[fatigue]]></category>
		<category><![CDATA[influence of loading intensity and speed on rubber deformation]]></category>
		<category><![CDATA[loading rate]]></category>
		<category><![CDATA[mathematical modeling of rubber ratcheting]]></category>
		<category><![CDATA[mean stress]]></category>
		<category><![CDATA[Mullins effect]]></category>
		<category><![CDATA[nitrile rubber]]></category>
		<category><![CDATA[Nitrile rubber cyclic deformation]]></category>
		<category><![CDATA[polymer mechanics]]></category>
		<category><![CDATA[predictive models for rubber material failure]]></category>
		<category><![CDATA[ratcheting behavior in elastomers]]></category>
		<category><![CDATA[ratcheting effect]]></category>
		<category><![CDATA[rubber material fatigue under repeated loading]]></category>
		<category><![CDATA[rubber sealing and vibration dampening durability]]></category>
		<category><![CDATA[stress amplitude]]></category>
		<category><![CDATA[stress-strain response of nitrile butadiene rubber]]></category>
		<guid isPermaLink="false">https://scienmag.com/?p=233794</guid>

					<description><![CDATA[A new experimental and modeling study reveals how stress amplitude, loading rate, and mean stress drive the cumulative ratcheting deformation of nitrile rubber, offering engineers a predictive tool for longer-lasting elastomer components.]]></description>
										<content:encoded><![CDATA[<p>Nitrile rubber is one of the most quietly essential materials in modern engineering. It seals fuel systems, cushions vibrating machinery, lines hoses in cars and aircraft, and holds up under years of repeated squeezing and releasing. Yet like every material subjected to cyclic loading, it has a hidden weakness: a slow, cumulative deformation known as ratcheting. When a rubber component is loaded and unloaded over and over, it does not simply return to its original shape each time. Instead, a small amount of strain accumulates cycle after cycle, and over thousands or millions of cycles that accumulated strain can become large enough to compromise the part. A team of researchers in China has now mapped out exactly how the intensity and speed of cyclic loading control this creeping failure mode in nitrile rubber, and they have built a modified mathematical model that can predict it.</p>
<p>The study, published in Polymer Bulletin by Yuanwen Liu, Jianlei Qi, Zheng Pan, Yu Qiao, Lei Dong, Jianyu Wu, and Yanping Wang, focuses on the ratcheting response of nitrile butadiene rubber, commonly abbreviated NBR. Ratcheting is a phenomenon engineers have studied intensively in metals, where cyclic stressing of pipelines, rails, and weld joints produces progressive plastic deformation that can ultimately trigger fatigue failure. In metals, sophisticated constitutive models exist to predict how quickly this deformation accumulates. Rubber, however, is a fundamentally different beast. It is a highly elastic material capable of enormous reversible deformation, often several hundred percent strain, and the models that work so well for steel and titanium simply do not transfer to elastomers without serious modification.</p>
<p>To understand why rubber ratcheting matters, it helps to picture what happens inside a rubber seal on an engine mount. Every vibration applies a stress pulse. If the peak stress is high enough, the polymer network and its reinforcing filler particles begin to rearrange. Some of that rearrangement is recovered when the load is removed, but some is not. The unrecovered portion is the ratcheting strain. In practical terms, a seal that ratchets will gradually change shape, lose its preload, and eventually leak or crack. Because NBR is the workhorse elastomer for oil-resistant applications, from O-rings to fuel line hoses, predicting its ratcheting behavior is directly relevant to product lifetime and safety.</p>
<p>The researchers designed a systematic experimental program to isolate the influence of each loading parameter. They varied the mean stress, which is the average stress level around which the cycle oscillates; the stress amplitude, which is how far the stress swings above and below that average; the stress loading rate, which is how quickly the stress is applied during each cycle; and the loading history, meaning the order in which different stress levels were applied. This kind of parametric study is essential because in real service, a rubber component rarely experiences a single, constant loading condition. It sees a messy combination of amplitudes, frequencies, and stress levels that change over its lifetime.</p>
<p>The results revealed a clear hierarchy of influence. Within the tested parameter range, the stress amplitude and the stress loading rate turned out to be the dominant factors controlling ratcheting strain. Higher stress amplitudes drove markedly more cumulative deformation, and so did slower loading rates. That second finding may seem counterintuitive at first glance, but it makes physical sense for a viscoelastic material. Rubber deforms through a combination of instantaneous elastic response and time-dependent viscous flow. When the stress is applied slowly, the polymer chains and filler networks have more time to flow and rearrange, so more of the deformation becomes permanent. When the stress is applied rapidly, the material behaves more stiffly and elastically, and less strain accumulates per cycle.</p>
<p>Mean stress, meanwhile, played a subtler but still critical role. When the peak stress of the cycle was held constant, or when the sequence of loading levels was considered, the mean stress had a more significant effect on the ratcheting behavior than the other parameters. This matters because two loading programs with the same peak stress can produce very different amounts of accumulated strain depending on where the cycle is centered. For designers, the practical implication is that specifying only a maximum operating stress is not enough to guarantee long-term dimensional stability; the entire stress waveform, including its baseline, must be considered.</p>
<p>The team also examined loading history, testing whether prior exposure to one stress level changed the material&#8217;s response to a subsequent level. This question is important because of the Mullins effect, a well-documented phenomenon in filled rubbers in which the first stretching of the material causes internal damage and softening, making the response to later loading history-dependent. The literature on filled elastomers shows that this induced softening and anisotropy can persist and interact with other inelastic mechanisms such as creep and stress relaxation. Understanding how loading sequence interacts with ratcheting is therefore a step toward more realistic lifetime predictions for components that experience variable duty cycles.</p>
<p>On the modeling side, the researchers confronted a fundamental problem: standard metal ratcheting models assume small deformations and are not applicable to large-deformation materials like rubber. Their solution was to introduce a deformation correction parameter, denoted as gamma, into the existing ratcheting framework. This parameter extends the applicability of the metal ratcheting model into the large-strain regime, allowing the model to successfully fit the ratcheting evolution of NBR under mean stress control. The resulting framework is phenomenological, meaning it captures the observed macroscopic behavior with fitted parameters rather than deriving it from molecular physics, but phenomenological models of this kind are exactly what engineering practice needs: compact, calibrated equations that can be implemented in finite element simulations of real components.</p>
<p>The significance of this work lies in bridging two research communities that have historically operated separately. The ratcheting literature is rich with studies of structural metals, including carbon steels, stainless steels, zirconium alloy tubes, magnesium alloys, and titanium, where ratcheting-fatigue interaction governs the life of pressurized pipes and welded joints. A parallel literature has documented ratcheting in polymers such as polycarbonate, PTFE, polyethylene, and PEEK, and in various filled rubbers including vulcanized natural rubber and its cerium-oxide-filled variants. By systematically quantifying how stress amplitude, loading rate, and mean stress shape the ratcheting of NBR, and by providing a corrected model tailored to highly elastic materials, the new study gives elastomer engineers a tool that metal engineers have enjoyed for decades.</p>
<p>The broader payoff could be substantial. Rubber components fail in service far more often through slow, cumulative degradation than through sudden overload, and ratcheting is a central mechanism in that degradation. A validated predictive model means manufacturers can simulate years of vibration and pressure cycling in software before a single seal is molded, screening designs for ratcheting resistance and optimizing compound formulations accordingly. It also means maintenance intervals can be set on a rational basis rather than conservative guesswork. The authors note that their framework could inform future analysis of highly elastic materials more generally, suggesting the correction-parameter approach may extend beyond NBR to other elastomers. As industries from aerospace to renewable energy push rubber components into harsher, longer-duty applications, understanding and predicting this quiet creep of matter under repeated stress becomes not just an academic exercise but a foundation for safer, longer-lasting machines.</p>
<p><strong>Subject of Research:</strong> Ratcheting deformation behavior of nitrile rubber under cyclic stress loading</p>
<p><strong>Article Title:</strong> Influences of stress amplitude and stress loading rate on the ratcheting response of nitrile rubber: experimental and numerical modeling</p>
<p><strong>Article References:</strong> Liu, Y., Qi, J., Pan, Z., Qiao, Y., Dong, L., Wu, J., &amp; Wang, Y. (2026). Influences of stress amplitude and stress loading rate on the ratcheting response of nitrile rubber: experimental and numerical modeling. <em>Polymer Bulletin, 83</em>(11), Article 621. <a href="https://doi.org/10.1007/s00289-026-06675-0" rel="noopener noreferrer">https://doi.org/10.1007/s00289-026-06675-0</a></p>
<p><strong>Image Credits:</strong> AI Generated</p>
<p><strong>DOI:</strong> <a href="https://doi.org/10.1007/s00289-026-06675-0" rel="noopener noreferrer">10.1007/s00289-026-06675-0</a></p>
<p><strong>Keywords:</strong> nitrile rubber, ratcheting effect, cyclic loading, stress amplitude, mean stress, loading rate, elastomers, constitutive modeling, polymer mechanics, fatigue, Mullins effect, deformation correction parameter</p>
]]></content:encoded>
					
		
		
		<post-id xmlns="com-wordpress:feed-additions:1">233794</post-id>	</item>
	</channel>
</rss>
