KAIST battery research – Science

KAIST Transforms Troublesome Protons into Battery Energy-Storage Resources

Faith Mcneil — Wed, 19 Aug 2026 04:29:21 +0000

A battery reaction long treated as a destructive side effect may become one of the keys to building safer, faster, and more energy-dense energy-storage systems. Researchers at the Korea Advanced Institute of Science and Technology (KAIST) have developed an electrode that deliberately uses both zinc ions and protons, storing them in a carefully controlled sequence rather than allowing them to interfere with one another. The strategy transforms protons—often blamed for damaging aqueous zinc-ion batteries—into an additional charge carrier capable of increasing the amount of energy the battery can store. The work could help advance water-based batteries for large-scale energy storage, where low cost, improved safety, and rapid operation are increasingly important.

Aqueous zinc-ion batteries use water-based electrolytes to transport charged particles between their electrodes. Unlike many lithium-based systems that rely on flammable organic solvents, water-based batteries carry a considerably lower fire risk and can potentially be manufactured from relatively abundant and inexpensive materials. These advantages have made them attractive for stationary energy-storage systems that collect electricity from renewable sources and release it when needed. Yet their practical performance has been limited by a fundamental trade-off: electrodes must accommodate enough ions to deliver high capacity while also allowing those ions to move rapidly during charging and discharging.

Zinc ions are appealing because each Zn²⁺ ion carries two units of positive charge, potentially contributing substantially to energy storage. However, their relatively large size and slower movement within an electrode can make it difficult to combine high capacity with fast operation. Protons, by comparison, are exceptionally small and can migrate through materials much more quickly. Their speed makes them attractive for rapid charge transfer, but protons have traditionally created serious problems in aqueous zinc-ion batteries. When they enter an electrode too early or in excessive numbers, they can trigger parasitic reactions and generate byproducts on the electrode surface. Those deposits can block pathways, disrupt zinc-ion transport, and gradually reduce battery performance.

Rather than suppressing proton activity, the KAIST team designed an electrode that controls when protons are allowed to participate. The material is a two-dimensional conductive metal–organic framework, or MOF, called Cu₃(HHTATP)₂. MOFs are porous crystalline structures assembled from metal centers and organic molecules, and their nanoscale channels can be chemically modified to influence how ions enter, move through, and bind within the material. In this case, the researchers introduced amine functional groups into the framework’s micropores. These chemical groups were designed to react with protons only after the electrode reached a specific voltage, effectively giving the material a built-in switching mechanism for sequential ion storage.

The result resembles filling a container with objects of different sizes. The electrode first stores the comparatively larger zinc ions while the battery operates in a higher-voltage range. As the voltage decreases, the amine groups become active and enable additional proton storage in the spaces and chemical environments that remain available. This order is crucial. If protons were admitted at the beginning of the process, they could generate surface byproducts before zinc ions had completed their storage step. By delaying proton participation, the electrode reduces competition between the two charge carriers and uses its porous architecture more efficiently.

Electrochemical measurements showed that zinc ions and protons contributed to energy storage in distinct voltage ranges. The research team used multiple X-ray analysis techniques to track the structural and chemical changes taking place inside the electrode, confirming that zinc ions were stored first and that protons entered afterward. The analyses also indicated that proton storage and release could be repeated, an important requirement for a rechargeable battery. Together, the results suggest that ion-storage sequence is not merely a side effect of electrode chemistry but can be deliberately engineered through molecular-level design.

The electrode achieved a storage capacity of 368.7 milliampere-hours per gram at a current density of 0.5 amperes per gram. Capacity expressed in milliampere-hours per gram indicates how much electrical charge can be stored per unit mass of active electrode material; a higher value means that a smaller quantity of material can hold more charge. The result is notable because aqueous zinc-ion batteries have often struggled to approach the combination of energy capacity and rapid ion transport associated with more established battery chemistries. By combining the charge contribution of zinc ions with the fast mobility of protons, the new material takes advantage of two different storage mechanisms within one electrode.

The material also retained 46.9 percent of its initial capacity when the charging and discharging rate was increased sixteenfold. Batteries commonly lose a significant portion of their storage capacity when operated rapidly because ions cannot move through the electrode quickly enough, and structural or chemical bottlenecks become more pronounced. Maintaining nearly half of the original capacity under such an accelerated condition suggests that the conductive two-dimensional framework and its controlled proton chemistry can support comparatively rapid electrochemical reactions. The electrode further maintained stable operation for more than 500 rapid charge–discharge cycles, indicating that the sequential process did not immediately destroy the material or permanently consume its proton-storage sites.

The study presents a broader design principle for battery research: ions that appear harmful under uncontrolled conditions may become useful when their reactions are separated in time and regulated by the molecular structure of an electrode. Professor Sarah S. Park, who led the KAIST research team, said that protons previously regarded as “troublemakers” could instead be used to store more energy, and that the principle might be applied to other electrode materials. The approach could be particularly relevant to large-scale energy-storage systems, where aqueous batteries offer safety and cost advantages but need higher energy density and faster response. The researchers now point toward the possibility of adapting sequential multi-ion storage to other porous conductive frameworks, potentially creating a new class of water-based batteries that combine rapid charging with greater energy storage.

Subject of Research: Sequential storage of zinc ions and protons in a conductive metal–organic framework for aqueous zinc-ion batteries.

Article Title: Sequential Zn²⁺–H⁺ Storage in a 2D Conductive Metal–Organic Framework for Advanced Aqueous Zinc-Ion Battery

Web References: https://doi.org/10.1016/j.chempr.2026.103129

References: Chem, DOI: 10.1016/j.chempr.2026.103129; article publication date: 7 July 2026.

Image Credits: KAIST

Keywords

Aqueous zinc-ion batteries, proton storage, zinc ions, metal–organic frameworks, conductive MOFs, Cu₃(HHTATP)₂, energy storage, fast charging, battery technology, sustainable batteries, large-scale energy storage, electrochemistry

KAIST Advances Giant Batteries Toward Commercialization for AI Data Centers

Faith Mcneil — Wed, 05 Aug 2026 01:49:20 +0000

The rapid expansion of artificial intelligence data centers is creating a new demand for energy-storage systems capable of operating at enormous scale. These facilities consume electricity continuously, placing pressure on power grids and increasing the need for systems that can store renewable energy and deliver it reliably when sunlight and wind power fluctuate. Researchers at the Korea Advanced Institute of Science and Technology (KAIST) have now reported a manufacturing advance that could bring one of the leading candidates for this role—vanadium redox flow batteries—closer to commercial deployment.

A KAIST team led by Professor Hee-Tak Kim has developed a faster and more stable method for producing the vanadium electrolyte used in these large batteries. The redesigned process reduces production time by approximately 67 percent, cutting it to about one-third of the duration required by the conventional method. The researchers say the approach also reduces impurities, lowers energy and equipment requirements, and allows the key catalyst to be reused more than 2,500 times without a significant loss of performance.

Vanadium redox flow batteries, or VRFBs, store energy in liquid electrolytes held in external tanks. During charging and discharging, the electrolytes flow through an electrochemical cell, where vanadium ions change their oxidation states and either absorb or release electrical energy. Unlike lithium-ion batteries, whose energy capacity is largely tied to the size and number of their cells, flow batteries can be expanded by increasing the volume of electrolyte in the tanks. This makes them particularly attractive for grid-scale storage, renewable-energy facilities, and data centers that require large reserves of electricity.

The technology also offers a safety advantage. VRFB electrolytes are water-based and nonflammable, substantially reducing the fire risks associated with many conventional battery systems. However, the chemical composition of the electrolyte must be carefully controlled for the battery to operate efficiently. The standard starting material has an average vanadium oxidation state of +3.5, commonly written as V3.5+. Producing this composition at industrial scale has traditionally been slow, expensive, and technically demanding.

The conventional manufacturing route uses two reduction stages. First, a chemical reducing agent—typically oxalic acid—causes vanadium ions to gain electrons, lowering their average oxidation state. The electrolyte is then subjected to electrochemical reduction, in which an electric current adjusts the remaining vanadium ions to the desired V3.5+ composition. That second stage requires a costly flow-battery stack and substantial electrical power, adding both capital expenses and operational complexity to the production process.

The KAIST researchers discovered that the problem was not limited to the final electrochemical step. Their analysis showed that the chemical reduction itself slows dramatically when the average oxidation state reaches approximately +4.1. This intermediate condition acts as a kinetic bottleneck: the reaction proceeds relatively efficiently before this point, but then decelerates sharply, much like traffic accumulating where a highway narrows. The slowdown extends the manufacturing process and limits the practicality of producing large quantities of electrolyte.

To bypass this bottleneck, the team combined chemical and catalytic reduction in a redesigned sequence. Chemical reduction is used during the earlier, faster stage, while a platinum-on-carbon catalyst, known as Pt/C, takes over when the vanadium reaches an average oxidation state of about +4.1. The catalytic route accelerates electron transfer through the slowest portion of the process, allowing the production system to avoid the rate-limiting region rather than forcing the chemical reaction to continue through it.

The new method also addresses a chemical-quality problem. Conventional processing can leave residual oxalic acid in the electrolyte, where it may act as an impurity and contribute to performance degradation inside the battery. By switching to catalytic reduction at the critical stage, the KAIST process eliminates the remaining oxalic acid while producing the targeted V3.5+ composition. According to the researchers, the Pt/C catalyst maintained its effectiveness through more than 2,500 reuse cycles, an important result for a process intended for industrial operation rather than laboratory-scale demonstrations.

“This study combined reaction engineering principles with thermodynamic predictions to identify the rate-determining step in the chemical reduction and redesigned the electrolyte production process to overcome this major bottleneck to the commercialization of large-scale batteries,” Kim said. The study, led by doctoral researcher Kyunghwa Seok, was published in Advanced Energy Materials under the title “Streamlined V3.5+ Electrolyte Production by Leveraging Chemical and Catalytic Reductions.” The authors say the advance could help reduce manufacturing costs and accelerate the use of vanadium flow batteries in AI data centers, renewable-energy installations, and other applications requiring dependable, long-duration energy storage.

Subject of Research: Vanadium redox flow battery electrolyte production and catalytic reduction processes

Article Title: Streamlined V3.5+ Electrolyte Production by Leveraging Chemical and Catalytic Reductions

Web References: https://doi.org/10.1002/aenm.71029

References: Kyunghwa Seok, Minseong Kang, and Hee-Tak Kim, Advanced Energy Materials

Image Credits: KAIST

Keywords

Vanadium redox flow batteries, VRFBs, energy storage, AI data centers, renewable energy, vanadium electrolyte, catalytic reduction, platinum-on-carbon catalyst, grid-scale batteries, long-duration energy storage