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	<title>haze &#8211; Science</title>
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	<title>haze &#8211; Science</title>
	<link>https://scienmag.com</link>
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		<title>Ammonia Emerges as Key Driver of Climate-Warming Brown Carbon in China&#8217;s Haze</title>
		<link>https://scienmag.com/ammonia-emerges-as-key-driver-of-climate-warming-brown-carbon-in-chinas-haze/</link>
		
		<dc:creator><![CDATA[Russell Cooper]]></dc:creator>
		<pubDate>Fri, 09 Oct 2026 15:36:01 +0000</pubDate>
				<category><![CDATA[Athmospheric]]></category>
		<category><![CDATA[Chemistry]]></category>
		<category><![CDATA[aerosol optics]]></category>
		<category><![CDATA[air quality]]></category>
		<category><![CDATA[ammonia]]></category>
		<category><![CDATA[Ammonia's role in atmospheric brown carbon formation]]></category>
		<category><![CDATA[aqueous-phase chemistry]]></category>
		<category><![CDATA[atmospheric chemistry of organic aerosols]]></category>
		<category><![CDATA[brown carbon]]></category>
		<category><![CDATA[chemical transformation of atmospheric pollutants]]></category>
		<category><![CDATA[Chinese winter haze pollution]]></category>
		<category><![CDATA[climate forcing]]></category>
		<category><![CDATA[climate impact of brown carbon]]></category>
		<category><![CDATA[haze]]></category>
		<category><![CDATA[imidazoles]]></category>
		<category><![CDATA[influence of ammonia on climate-warming aerosols]]></category>
		<category><![CDATA[light absorption by brown carbon]]></category>
		<category><![CDATA[nitro-aromatic compounds]]></category>
		<category><![CDATA[nitrogen-containing organic compounds in haze]]></category>
		<category><![CDATA[nitrogenous organic compounds]]></category>
		<category><![CDATA[North China Plain]]></category>
		<category><![CDATA[optical properties of atmospheric aerosols]]></category>
		<category><![CDATA[particulate matter and climate change]]></category>
		<category><![CDATA[policy implications of ammonia emission reduction]]></category>
		<category><![CDATA[regional air pollution in North China Plain]]></category>
		<category><![CDATA[secondary organic aerosol]]></category>
		<guid isPermaLink="false">https://scienmag.com/?p=254633</guid>

					<description><![CDATA[A five-site winter study across the North China Plain shows that nitrogenous organic compounds formed through ammonia-driven aqueous reactions are the dominant light-absorbing chromophores in brown carbon, pointing to ammonia emission control as essential for further haze mitigation.]]></description>
										<content:encoded><![CDATA[<p>Deep in the winter haze that blankets the North China Plain, an invisible chemical transformation is taking place that could reshape how scientists think about air pollution and climate. A team of Chinese researchers has now shown that nitrogen-containing organic compounds, formed largely through reactions driven by ammonia, are the pivotal light-absorbing molecules governing the optical behavior of atmospheric brown carbon across this densely populated region. The finding, published in Atmospheric Chemistry and Physics, carries a striking policy implication: cutting ammonia emissions, long treated as a secondary concern compared with sulfur dioxide and nitrogen oxides, may be essential for finally clearing the region&#8217;s stubborn winter haze and reducing its climate impact.</p>
<p>Brown carbon, often abbreviated BrC, is the enigmatic cousin of black carbon. While black carbon is the familiar soot that absorbs sunlight across the entire visible spectrum, brown carbon is a complex brew of organic molecules that absorbs light selectively, with its absorbance climbing steeply toward ultraviolet wavelengths. This wavelength dependence makes brown carbon both scientifically fascinating and difficult to model. Recent modeling studies suggest that brown carbon accounts for more than twenty percent of the direct radiative effect caused by carbonaceous aerosols, and in some regions, such as the remote tropical upper troposphere, it may even dominate that effect. Beyond its climatic role, brown carbon can suppress the ultraviolet sunlight that drives tropospheric photochemistry, slowing the photolysis of ozone and radicals, and some of its chromophores, including polycyclic aromatic and nitro-heterocyclic compounds, carry significant oxidative potential with consequences for human health.</p>
<p>The new study, led by Can Wu and Gehui Wang of East China Normal University together with colleagues, set out to resolve a puzzle. Over the past decade, China has implemented stringent emission controls in the North China Plain, shifting residential heating from coal to natural gas and electricity, eliminating small coal-fired industrial boilers, and banning straw burning. Given that primary emissions from incomplete combustion are a major source of brown carbon, its levels should have plummeted. Yet strongly light-absorbing brown carbon kept appearing in high concentrations across the region. To understand why, the team conducted simultaneous measurements at five sites during the winter of 2023, from mid-November through the end of December: the cities of Beijing, Tianjin, Handan and Jinan, plus a rural station near Luancheng free from significant industrial influence. At each site, fine particulate matter smaller than 2.5 micrometers was collected every twelve hours onto prebaked quartz filters mounted on rooftops fifteen to twenty meters above the ground.</p>
<p>The spatial patterns the team uncovered were revealing. The average light absorption coefficient at 365 nanometers, a standard metric for water-soluble brown carbon, was highest at the rural Luancheng site, reaching 8.0 plus or minus 4.7 megapercubic megameter, roughly 1.1 to 3.5 times higher than at the urban sites. Beijing recorded the lowest value at just 2.3 plus or minus 1.9. Across the four urban sites, average light absorption had declined by about forty-five percent between 2018 and 2023, and in Beijing the value was only sixteen percent of what it had been a decade earlier, when the city&#8217;s average fine particle concentration stood at 158 micrograms per cubic meter compared with roughly a quarter of that during this campaign. The clean air actions, in other words, are visibly working. Yet multi-day haze episodes with hourly peaks reaching 203 micrograms per cubic meter, nearly three times the national grade-II standard of 75, still struck all five sites simultaneously, confirming that regional pollution remains a persistent winter challenge, particularly in the south.</p>
<p>When the researchers normalized absorption by the amount of water-soluble organic carbon, producing the mass absorption efficiency, a distinctly different spatial picture emerged. Jinan recorded the strongest light absorptivity of any site, at 1.40 plus or minus 0.02 square meters per gram, a value on par with severely polluted regions such as Xingtai, Xi&#8217;an and Delhi, India, and squarely within the range documented for brown carbon emitted from residential bituminous coal combustion. Tianjin, Luancheng and Handan shared values near 1.1 square meters per gram, closely matching biomass-burning-derived brown carbon, and concentration-weighted trajectory analysis linked their high absorption loadings to regions dense with satellite-detected fire hotspots. Beijing, by contrast, showed the weakest absorptivity at 0.71 square meters per gram, likely a combination of vehicle emissions, which typically produce weakly absorbing brown carbon, and atmospheric aging, since the ratio of the stable benzo[e]pyrene to its easily degraded counterpart benzo[a]pyrene indicated Beijing&#8217;s aerosol was the most chemically aged, and aging is known to bleach brown carbon&#8217;s color over time.</p>
<p>The pivotal insight came when the team compared clean periods, when fine particle concentrations stayed below 75 micrograms per cubic meter, with haze periods above that threshold. At most sites, the light absorptivity of water-soluble brown carbon increased as haze developed, and this enhancement tracked a parallel rise in the ratio of nitrogen to carbon within the water-soluble organic fraction. A positive correlation between that nitrogen-to-carbon ratio and light absorption held across the entire region, and a high nitrogen-to-carbon ratio also coincided with an elevated ratio of water-soluble to total organic carbon, a fingerprint of secondary formation. Together, these patterns pointed to nitrogenous organic compounds, or NOCs, as the crucial chromophores modulating brown carbon&#8217;s optical properties, and to secondary atmospheric production, rather than direct emissions, as their dominant source. A tracer-based apportionment confirmed the point: secondary formation explained roughly 64 plus or minus 21 percent of the water-soluble organic nitrogen in Beijing, comparable to other urban sites and about 1.2 times the rural fraction, and the secondary share grew as pollution intensified.</p>
<p>To identify what drives the formation of this secondary organic nitrogen, the researchers turned to machine learning. A random forest model, trained on seventy percent of the dataset and validated with ten-fold cross-correlation, attributed roughly forty-eight percent of the variance in secondary water-soluble organic nitrogen to ammonium and about twenty-eight percent to aerosol liquid water content, with a generalized additive model independently confirming both factors. The statistical evidence aligned with chemistry: reactions of ammonia or ammonium with atmospheric dicarbonyls such as glyoxal and methylglyoxal are a well-established pathway to light-absorbing nitrogen heterocycles like imidazoles, and laboratory work has shown that the uptake of these dicarbonyls, and the resulting yields of nitrogen-containing products and their oligomers, are significantly higher on neutral ammonium sulfate seeds than on acidic ammonium bisulfate. Thermodynamic calculations indicated the region&#8217;s aerosols were indeed dominated by ammonium sulfate and ammonium nitrate. During a humid haze episode in late December, offline aerosol mass spectrometry detected imidazole-related fragment ions that correlated strongly with ammonium, with a coefficient of determination of 0.93, but not with combustion tracers, and the ratio of these fragments to organic nitrogen climbed dramatically as the episode evolved, all pointing to ammonia-driven aqueous chemistry as the dominant formation route under moist conditions.</p>
<p>Aerosol acidity added a further layer of nuance. The mass fraction of secondary organic nitrogen correlated negatively with aerosol pH, suggesting that mildly acidic conditions favor nitrogenous chromophore formation, plausibly because ammonia partitions more readily into acidic particles, and because carbonyl-ammonia reactions are generally acid catalyzed. The team&#8217;s partitioning calculations showed that the fraction of ammonia present in the gas phase at pH 3.0 was an order of magnitude higher than at pH 5.0, consistent with this picture. Gas-phase photochemistry contributed too: nitrogen dioxide and ozone together explained over fourteen percent of the variance in secondary organic nitrogen, and nine quantified nitro-aromatic compounds, dominated by 4-nitrophenol and 4-nitrocatechol, were formed roughly forty-six to sixty-four percent by secondary oxidation, correlating with nitrogen dioxide rather than with biomass-burning tracers and displaying a temperature dependence consistent with gas-to-particle partitioning theory.</p>
<p>The broader implications stretch well beyond the North China Plain. A recent modeling study cited by the authors suggests that nitrogen-containing compounds dominate global organic aerosol absorption, accounting for eighteen percent of the direct radiative effect induced by carbonaceous aerosols, and previous work by the same group has shown that ammonia-driven aqueous reactions can generate brown carbon even in lifting air masses aloft. If ammonia is one of the key factors sustaining high loadings of strongly absorbing brown carbon across China&#8217;s boundary layer, then the persistently high ammonia loadings from insufficiently controlled agricultural emissions represent a blind spot in current air quality strategy. As the authors conclude, targeted ammonia emission control may prove indispensable for further mitigating wintertime haze and brown carbon pollution in ammonia-rich regions, especially during moist haze episodes when abundant aerosol liquid water opens the door to the aqueous chemistry that turns invisible organic vapors into climate-warming, light-absorbing particles.</p>
<p><strong>Subject of Research:</strong> Light absorption and formation mechanisms of water-soluble brown carbon aerosols in the North China Plain</p>
<p><strong>Article Title:</strong> Light absorption properties and composition of water-soluble brown carbon in North China Plain: implication for an enhancing role of nitrogenous organic compounds</p>
<p><strong>Article References:</strong> Light absorption properties and composition of water-soluble brown carbon in North China Plain: implication for an enhancing role of nitrogenous organic compounds. (n.d.). <a href="https://doi.org/10.5194/acp-26-14229-2026" rel="noopener noreferrer">https://doi.org/10.5194/acp-26-14229-2026</a></p>
<p><strong>Image Credits:</strong> AI Generated</p>
<p><strong>DOI:</strong> <a href="https://doi.org/10.5194/acp-26-14229-2026" rel="noopener noreferrer">10.5194/acp-26-14229-2026</a></p>
<p><strong>Keywords:</strong> brown carbon, ammonia, nitrogenous organic compounds, haze, North China Plain, aerosol optics, secondary organic aerosol, aqueous-phase chemistry, imidazoles, nitro-aromatic compounds, air quality, climate forcing</p>
]]></content:encoded>
					
		
		
		<post-id xmlns="com-wordpress:feed-additions:1">254633</post-id>	</item>
		<item>
		<title>China&#8217;s Clean Air Push Curbed Winter PAH Pollution, but Hidden Oxidized Toxins Linger</title>
		<link>https://scienmag.com/chinas-clean-air-push-curbed-winter-pah-pollution-but-hidden-oxidized-toxins-linger/</link>
		
		<dc:creator><![CDATA[Russell Cooper]]></dc:creator>
		<pubDate>Mon, 05 Oct 2026 21:42:24 +0000</pubDate>
				<category><![CDATA[Climate]]></category>
		<category><![CDATA[air quality]]></category>
		<category><![CDATA[atmospheric chemistry of smog]]></category>
		<category><![CDATA[biomass burning]]></category>
		<category><![CDATA[carcinogenic air pollutants]]></category>
		<category><![CDATA[China air pollution reduction]]></category>
		<category><![CDATA[Clean Air Action]]></category>
		<category><![CDATA[emerging pollutants in winter air quality]]></category>
		<category><![CDATA[Fenwei Plain]]></category>
		<category><![CDATA[haze]]></category>
		<category><![CDATA[health risk]]></category>
		<category><![CDATA[impact of Clean Air Action plan]]></category>
		<category><![CDATA[indoor and outdoor air quality]]></category>
		<category><![CDATA[OPAHs]]></category>
		<category><![CDATA[oxidized toxins in haze]]></category>
		<category><![CDATA[PAHs]]></category>
		<category><![CDATA[PM2.5]]></category>
		<category><![CDATA[PM2.5 health effects]]></category>
		<category><![CDATA[polycyclic aromatic hydrocarbons PAHs]]></category>
		<category><![CDATA[public health implications of air pollution]]></category>
		<category><![CDATA[regulation of toxic airborne compounds]]></category>
		<category><![CDATA[source apportionment]]></category>
		<category><![CDATA[toxic equivalency]]></category>
		<category><![CDATA[winter haze pollution in Xi'an]]></category>
		<category><![CDATA[Xi'an]]></category>
		<guid isPermaLink="false">https://scienmag.com/?p=239340</guid>

					<description><![CDATA[A new study of winter air in Xi'an shows China's Clean Air Action has lowered particle-bound PAH pollution, but oxidized derivatives called OPAHs surge during haze episodes and dominate the toxic burden.]]></description>
										<content:encoded><![CDATA[<p>In the ancient city of Xi&#8217;an, where winter haze once blanketed the terracotta warriors and the crowded streets of the Fenwei Plain in a gray shroud, the air has quietly changed. A new study published in the journal Environmental Geochemistry and Health offers one of the most detailed looks yet at how China&#8217;s sweeping Clean Air Action plan has reshaped the invisible chemistry of winter smog in an inland basin city. The findings are both encouraging and cautionary: levels of the most notorious particle-bound carcinogens have fallen compared with the pre-policy era, yet a related family of oxidized compounds, often overlooked by regulators, surges during haze episodes and now dominates the toxic burden carried on fine particles.</p>
<p>The research team, led by Shun Xiao of Shaanxi Normal University together with colleagues from the Chinese Academy of Sciences and partner institutions, focused on fine particulate matter known as PM2.5, particles smaller than 2.5 micrometers that penetrate deep into the lungs. Suspended on these particles are polycyclic aromatic hydrocarbons, or PAHs, a class of organic molecules formed whenever carbon-based fuels burn incompletely. PAHs include compounds such as benzo[a]pyrene that are classified as probable human carcinogens. But the team went a step further and also measured oxygenated polycyclic aromatic hydrocarbons, or OPAHs, the oxidized derivatives produced when parent PAHs react with ozone, nitrogen oxides, and other atmospheric oxidants. These derivatives have received far less regulatory attention, even though laboratory studies suggest many of them are more mutagenic, more persistent, and more soluble than their parent compounds.</p>
<p>The study&#8217;s historical comparison delivered the headline result: wintertime PAH concentrations in Xi&#8217;an have generally declined during the years of China&#8217;s clean air actions. This is a meaningful signal for a city whose geography works against it. Xi&#8217;an sits in a basin on the Guanzhong Plain, hemmed in by the Qinling Mountains to the south and the Loess Plateau to the north. In winter, temperature inversions trap cold, dense air near the surface like a lid on a pot, allowing emissions from heating, traffic, and industry to accumulate for days. That a basin city with such unfavorable dispersion conditions has still seen PAH levels fall suggests that emission controls, rather than favorable weather alone, have driven the improvement.</p>
<p>To understand where the remaining pollution comes from, the researchers applied a statistical source-apportionment technique called positive matrix factorization, or PMF. The method disentangles the chemical fingerprints of different emission sources by analyzing the relative abundances of dozens of individual PAH and OPAH species. The results pointed to a mixed picture, with biomass-burning-related mixed combustion emerging as the single largest contributor. In practical terms, the burning of wood, crop residues, and other solid fuels for residential heating and cooking remains the dominant engine of wintertime PAH pollution in the region, alongside contributions from traffic and industrial sources. This matters because residential solid-fuel combustion is notoriously difficult to regulate: millions of households in northern China still rely on it, and emissions occur at low temperatures that favor the formation of both parent PAHs and their oxygenated derivatives.</p>
<p>One of the most technically intriguing findings concerns what happens during haze episodes. When the researchers compared clear days with heavy pollution episodes, they found that absolute concentrations of both PAHs and OPAHs increased, but the increase was statistically significant only for the OPAHs. The parent PAHs rose, but not in a way that stood apart from normal variability. The chemical profiles also told a story: four- and five-ring PAHs dominated the parent compound profile, while a specific OPAH called benzanthrone, abbreviated BcdPQ, dominated the oxidized fraction. This asymmetry suggests that during stagnant, polluted conditions, atmospheric oxidation processes actively transform PAHs into their oxygenated counterparts, so the toxic chemistry of the haze evolves even as emissions stay roughly constant. Secondary formation, in other words, amplifies the oxidized fraction precisely when people are breathing the most polluted air.</p>
<p>Meteorology emerged as a powerful controlling factor. The team found that pollutant concentrations were strongly associated with synoptic-scale pressure patterns, the large-scale weather systems that determine wind speed, boundary-layer height, and atmospheric stability. When high-pressure systems settle over the region, calm winds and suppressed vertical mixing allow locally emitted pollutants to build up. The analysis of regional transport added another layer: pollution in the basin was dominated by accumulation within the basin itself, combined with short-range transport from industrial zones in northern Shaanxi. This finding has direct policy implications, because it means that even aggressive local controls in Xi&#8217;an cannot fully protect the city without coordinated management of upwind industrial emissions across the province.</p>
<p>To translate chemistry into health terms, the researchers calculated toxic-equivalent concentrations, a metric that weights each PAH species by its carcinogenic potency relative to benzo[a]pyrene. During haze periods, these toxic-equivalent concentrations were markedly higher, and, strikingly, the OPAHs, particularly BcdPQ, dominated the toxicity-equivalent burden. This is a result that should make regulators pause. Conventional air quality management targets PM2.5 mass and a short list of priority PAHs, yet the compounds contributing the largest share of the calculated toxic load during the worst pollution episodes may fall outside that list entirely. If oxidized derivatives carry much of the risk, then policies that reduce particle mass without curbing the precursors and oxidation conditions that generate OPAHs may overstate the health benefits achieved.</p>
<p>The team also performed screening-level estimates of the incremental lifetime cancer risk, or ILCR, a standard metric that estimates the additional probability of developing cancer over a lifetime of exposure. The estimates generally remained below the commonly used threshold of one in ten thousand, a level often treated as an upper bound of acceptable risk. However, the risks increased during haze episodes, and the elevation was most pronounced for adults and elderly groups, who breathe larger volumes of air and accumulate greater lifetime exposure. While the screening-level nature of the calculation means the absolute numbers should be interpreted with care, the pattern is clear: the episodes that produce the worst visibility also produce the highest estimated risk, and the most vulnerable populations bear the largest share.</p>
<p>The broader context makes the study timely. China&#8217;s Clean Air Action plan, launched in 2013 and strengthened in subsequent phases, has achieved documented reductions in PM2.5 concentrations across much of the country, and recent national bulletins report continued improvement in overall air quality. Yet researchers have begun to warn that the easy gains may be over. Studies from other regions, including the Yangtze River Delta, have documented prolonged winter haze events even in the post-action-plan era, and analyses of decadal PAH trends confirm that source profiles are shifting as coal gives way to biomass burning, gas, and electricity in the residential sector. Xi&#8217;an&#8217;s experience illustrates this transition: the city&#8217;s air is cleaner by the measures that policy was designed to improve, but the residual pollution is increasingly shaped by sources that are diffuse, household-level, and chemically transformed in the atmosphere.</p>
<p>What should happen next, according to the study&#8217;s conclusions, is a targeted second wave of controls. The authors argue that stronger measures against residential biomass and other solid-fuel combustion, tighter management of traffic emissions, and explicit attention to the atmospheric formation of OPAHs remain necessary in the Fenwei Plain. That would mean accelerating clean heating conversions in rural households around the basin, coordinating industrial emission controls across northern Shaanxi, and expanding the suite of monitored compounds to include oxygenated derivatives whose toxicity may rival or exceed that of the parent PAHs. For a city that has spent a decade clawing back its winter skies, the message is one of progress with a chemical asterisk: the haze is thinner than it used to be, but what remains of it is, in the most toxic sense, not the same haze at all.</p>
<p><strong>Subject of Research:</strong> PM2.5-bound PAHs and OPAHs pollution, sources, and health risks in Xi&#x27;an under China&#x27;s Clean Air Action plan</p>
<p><strong>Article Title:</strong> Pollution characteristics and health risks of PAHs and OPAHs in PM2.5 of an inland basin city in China under the influence of the clean air action plan</p>
<p><strong>Article References:</strong> Xiao, S., Luo, X., Li, J., Zhang, N., Liu, S., Du, W., Liu, J., &amp; Yang, L. (2026). Pollution characteristics and health risks of PAHs and OPAHs in PM2.5 of an inland basin city in China under the influence of the clean air action plan. <em>Environmental Geochemistry and Health, 48</em>(14), Article 566. <a href="https://doi.org/10.1007/s10653-026-03449-5" rel="noopener noreferrer">https://doi.org/10.1007/s10653-026-03449-5</a></p>
<p><strong>Image Credits:</strong> AI Generated</p>
<p><strong>DOI:</strong> <a href="https://doi.org/10.1007/s10653-026-03449-5" rel="noopener noreferrer">10.1007/s10653-026-03449-5</a></p>
<p><strong>Keywords:</strong> PM2.5, PAHs, OPAHs, haze, Clean Air Action, Xi&#x27;an, Fenwei Plain, source apportionment, biomass burning, health risk, toxic equivalency, air quality</p>
]]></content:encoded>
					
		
		
		<post-id xmlns="com-wordpress:feed-additions:1">239340</post-id>	</item>
		<item>
		<title>Haze Trapped Fossil CO2 During Xi&#8217;an Lockdown, Isotope Study Reveals</title>
		<link>https://scienmag.com/haze-trapped-fossil-co2-during-xian-lockdown-isotope-study-reveals/</link>
		
		<dc:creator><![CDATA[Russell Cooper]]></dc:creator>
		<pubDate>Wed, 30 Sep 2026 19:26:18 +0000</pubDate>
				<category><![CDATA[Chemistry]]></category>
		<category><![CDATA[Air pollution]]></category>
		<category><![CDATA[atmospheric isotope analysis during pandemic]]></category>
		<category><![CDATA[carbon isotope forensics in pollution sources]]></category>
		<category><![CDATA[carbon-13]]></category>
		<category><![CDATA[carbon-14]]></category>
		<category><![CDATA[challenges in measuring true fossil fuel emissions]]></category>
		<category><![CDATA[COVID-19 lockdown]]></category>
		<category><![CDATA[fossil fuel CO2]]></category>
		<category><![CDATA[haze]]></category>
		<category><![CDATA[haze effects on atmospheric CO2 measurements]]></category>
		<category><![CDATA[impact of lockdown on city air quality]]></category>
		<category><![CDATA[implications for climate monitoring accuracy]]></category>
		<category><![CDATA[isotope study of fossil fuel CO2]]></category>
		<category><![CDATA[meteorology]]></category>
		<category><![CDATA[natural experiments in urban pollution]]></category>
		<category><![CDATA[radiocarbon]]></category>
		<category><![CDATA[source apportionment]]></category>
		<category><![CDATA[top-down verification of carbon inventories]]></category>
		<category><![CDATA[urban carbon emissions analysis]]></category>
		<category><![CDATA[urban emissions]]></category>
		<category><![CDATA[ventilation coefficient]]></category>
		<category><![CDATA[weather influence on greenhouse gas readings]]></category>
		<category><![CDATA[Xi'an]]></category>
		<category><![CDATA[Xi'an COVID-19 lockdown environmental study]]></category>
		<guid isPermaLink="false">https://scienmag.com/?p=218510</guid>

					<description><![CDATA[A new isotope study of Xi'an's coronavirus lockdown shows haze episodes raised fossil carbon dioxide concentrations by 159 percent over ventilated days, revealing how meteorology can bias urban emissions assessments.]]></description>
										<content:encoded><![CDATA[<p>When China imposed coronavirus lockdowns in the winter of 2021 and 2022, cities fell unusually quiet. Traffic thinned, factories slowed, and scientists around the world seized the moment as a rare natural experiment in urban carbon emissions. Yet a new study from Xi&#8217;an, a sprawling metropolis in northwestern China, shows that reading the atmosphere during such an event is far trickier than simply watching concentrations fall. According to research published in Environmental Chemistry Letters, haze episodes during the lockdown drove concentrations of fossil fuel carbon dioxide up by 159 percent compared with well-ventilated, non-haze days, even as actual emissions collapsed. The finding is a stark warning that weather can masquerade as emissions, potentially skewing the top-down assessments that cities and nations rely on to verify their carbon accounts.</p>
<p>The research team, led by Jiaqi Zhang and Zhenchuan Niu of the Institute of Earth Environment at the Chinese Academy of Sciences, sampled air at an urban site in Xi&#8217;an&#8217;s High-Tech Zone every day from December 23, 2021, to January 23, 2022, a window covering the city&#8217;s strict pandemic confinement. Rather than relying on total carbon dioxide readings, which mix natural and human sources, the researchers turned to isotopic forensics. Fossil fuels contain no carbon-14, the radioactive isotope of carbon that decays over tens of thousands of years, so carbon derived from coal, oil, and natural gas is distinctly radiocarbon-free. By measuring the carbon-14 composition of atmospheric carbon dioxide, the team could isolate the fossil component with precision, a technique long championed for monitoring megacity emissions.</p>
<p>The isotopic measurements were complemented by analysis of carbon-13, the stable heavy isotope of carbon. Different carbon sources carry different carbon-13 signatures: vehicle exhaust, coal combustion, and natural gas each leave a characteristic fingerprint in the carbon dioxide they release. By combining the two isotope systems, the researchers could not only quantify how much fossil carbon dioxide was in the air but also apportion it among its sources. This dual-isotope approach, normalized against a ventilation coefficient, formed the analytical backbone of the study and allowed the team to separate genuine changes in emissions from changes in how the atmosphere diluted them.</p>
<p>That ventilation correction proved to be the crux of the work. The ventilation coefficient, a classical concept in air pollution meteorology dating back to the work of Holzworth in the 1960s, combines the depth of the atmospheric mixing layer with the near-surface wind speed. When the mixing layer is shallow and winds are calm, pollutants emitted at the surface accumulate rapidly; when the boundary layer is deep and winds are brisk, the same emissions are swept away. Winter haze episodes in northern Chinese cities are typically triggered by exactly such stagnant conditions, with temperature inversions capping the boundary layer and trapping everything from fine particulate matter to greenhouse gases near the ground.</p>
<p>The Xi&#8217;an data captured this dynamic in dramatic fashion. During haze periods within the lockdown, fossil carbon dioxide concentrations were 159 percent, give or take 48 percent, higher than during non-haze periods, despite the fact that human activity, and presumably emissions, were suppressed throughout. In other words, the atmosphere itself, not the sources, was responsible for a large share of the variation observed at the sampling site. Without accounting for this meteorological amplification, an observer relying on concentration data alone would have dramatically misjudged how emissions were changing during the lockdown.</p>
<p>Once the team normalized the measurements with the ventilation coefficient, the true emissions signal emerged. Compared with the period after the lockdown ended, fossil carbon dioxide concentrations during well-ventilated, non-haze lockdown days fell by 63.0 percent, with an uncertainty of 10.6 percent. Averaged across the entire lockdown period, including hazy days, the ventilation-normalized decline was 48.8 percent, plus or minus 12.2 percent. These figures align with the substantial reductions in traffic and economic activity that characterized the confinement, and they demonstrate how powerful the isotope-based method can be when meteorological variability is properly handled.</p>
<p>The carbon-13 source apportionment added a second layer of insight into which activities drove the decline. Vehicle emissions dropped by 84.6 percent, with a relatively tight uncertainty of 4.7 percent, reflecting the near-standstill of urban traffic during confinement. Coal burning emissions, by contrast, decreased by only 31.2 percent, though with a much larger uncertainty of 20.3 percent. The asymmetry makes physical sense: private and commercial transport can be switched off almost entirely by lockdown orders, whereas residential and industrial coal combustion for heating continues through the frigid Shaanxi winter regardless of pandemic restrictions. Xi&#8217;an, like much of northern China, still depends significantly on coal for winter heating, and that dependence cushioned the overall emissions decline.</p>
<p>The study&#8217;s implications reach well beyond one city or one lockdown. Since the pandemic began, researchers have used atmospheric observations to estimate emissions changes from the COVID-19 confinement in locations from California to Hungary, and global datasets such as the Carbon Monitor have tracked near-real-time emission shifts worldwide. Many of these assessments rely on top-down approaches, in which measured atmospheric concentrations are converted into emission estimates using atmospheric transport models. The Xi&#8217;an results show that meteorological effects, particularly haze-induced stagnation, can substantially bias such top-down assessments if not explicitly corrected. A city might appear to have slashed its emissions when in fact stagnant air was simply concentrating them, or vice versa.</p>
<p>The methodological lesson is that concentration is not emission, and the gap between the two is governed by the vagaries of weather. For urban carbon monitoring networks being built to verify climate pledges, the Xi&#8217;an study suggests that radiocarbon measurements, paired with careful boundary-layer and wind observations, offer a robust path forward. The ventilation coefficient normalization used here is simple enough to be applied broadly, yet it transformed a potentially misleading haze signal into a clean measurement of a 63 percent emissions drop. As cities worldwide deploy increasingly dense greenhouse gas sensing networks, incorporating such meteorological corrections will be essential to distinguish real mitigation progress from atmospheric illusion.</p>
<p>There is also a human story embedded in the dataset. The authors acknowledge an e-bike courier who assisted with sample collection during the pandemic, a reminder that the daily air samples underpinning these isotope measurements were gathered under difficult confinement conditions. The work was supported by the National Natural Science Foundation of China, the Natural Science Basic Research Program of Shaanxi, and the Strategic Priority Research Program of the Chinese Academy of Sciences. Published on September 29, 2026, the study stands as both a detailed case study of a locked-down megacity and a methodological caution: when the air stagnates, the atmosphere can tell a story about emissions that is dramatically at odds with reality, and only isotope forensics combined with meteorological insight can set the record straight.</p>
<p><strong>Subject of Research:</strong> Isotopic quantification of fossil fuel carbon dioxide emissions and meteorological haze effects during the COVID-19 lockdown in Xi&#x27;an</p>
<p><strong>Article Title:</strong> Substantial increase of fossil carbon dioxide concentrations in haze time periods versus ventilated non-haze periods during the coronavirus lockdown in Xi’an</p>
<p><strong>Article References:</strong> Zhang, J., Liang, D., Niu, Z., Zhou, W., Wang, P., Feng, X., Wu, S., Wang, G., Lyu, M., Lu, X., &amp; Kong, X. (2026). Substantial increase of fossil carbon dioxide concentrations in haze time periods versus ventilated non-haze periods during the coronavirus lockdown in Xi’an. <em>Environmental Chemistry Letters</em>. <a href="https://doi.org/10.1007/s10311-026-01927-x" rel="noopener noreferrer">https://doi.org/10.1007/s10311-026-01927-x</a></p>
<p><strong>Image Credits:</strong> AI Generated</p>
<p><strong>DOI:</strong> <a href="https://doi.org/10.1007/s10311-026-01927-x" rel="noopener noreferrer">10.1007/s10311-026-01927-x</a></p>
<p><strong>Keywords:</strong> COVID-19 lockdown, fossil fuel CO2, carbon-14, carbon-13, haze, ventilation coefficient, source apportionment, urban emissions, Xi&#x27;an, meteorology, radiocarbon, air pollution</p>
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		<title>Three-Year Campus Study Reveals How Bangkok&#8217;s Haze Season Seeps Into University Buildings</title>
		<link>https://scienmag.com/three-year-campus-study-reveals-how-bangkoks-haze-season-seeps-into-university-buildings/</link>
		
		<dc:creator><![CDATA[Russell Cooper]]></dc:creator>
		<pubDate>Sat, 26 Sep 2026 17:04:59 +0000</pubDate>
				<category><![CDATA[Chemistry]]></category>
		<category><![CDATA[air quality in megacity campuses]]></category>
		<category><![CDATA[air quality index]]></category>
		<category><![CDATA[Bangkok]]></category>
		<category><![CDATA[Bangkok haze season]]></category>
		<category><![CDATA[effects of haze on academic environments]]></category>
		<category><![CDATA[environmental pollution in Bangkok]]></category>
		<category><![CDATA[exposure assessment]]></category>
		<category><![CDATA[haze]]></category>
		<category><![CDATA[health risks of fine particulate matter]]></category>
		<category><![CDATA[indoor air pollution]]></category>
		<category><![CDATA[indoor air quality]]></category>
		<category><![CDATA[indoor-outdoor air exchange]]></category>
		<category><![CDATA[inhaled dose]]></category>
		<category><![CDATA[long-term air quality monitoring]]></category>
		<category><![CDATA[low-cost laser sensors for air quality]]></category>
		<category><![CDATA[particulate matter]]></category>
		<category><![CDATA[particulate matter infiltration in university buildings]]></category>
		<category><![CDATA[PM10]]></category>
		<category><![CDATA[PM2.5]]></category>
		<category><![CDATA[tropical megacity]]></category>
		<category><![CDATA[tropical university indoor air]]></category>
		<category><![CDATA[university buildings]]></category>
		<category><![CDATA[urban air pollution impact]]></category>
		<category><![CDATA[WHO air quality guidelines]]></category>
		<guid isPermaLink="false">https://scienmag.com/?p=216297</guid>

					<description><![CDATA[A three-year monitoring campaign at Chulalongkorn University in Bangkok shows that seasonal haze and traffic pollution infiltrate university buildings, with indoor-to-outdoor ratios varying dramatically by building design and ventilation.]]></description>
										<content:encoded><![CDATA[<p>Fine particulate matter is one of the most insidious pollutants in modern cities, small enough to slip past the body&#8217;s natural defenses and lodge deep in the lungs. While most people assume that stepping indoors offers an escape from urban smog, a new three-year study from Chulalongkorn University in Bangkok shows that the boundary between outdoor and indoor air is far more porous than many would like to believe. By continuously monitoring particulate matter inside and outside four campus buildings between August 2022 and July 2025, researchers have produced one of the longest paired indoor-outdoor air quality records ever assembled for a tropical university environment, and the results carry a warning for anyone who lives or works in a rapidly urbanizing megacity.</p>
<p>The research team, led by Mushtaq Ahmad and Sirima Panyametheekul, deployed low-cost laser particle sensors at four distinct locations across the Chulalongkorn University campus: the School of Agricultural Resources, the Chulalongkorn University Language Institute, the Central Library, and the Chamchuri 10 building, also known as the UltimateX Library. These sites were deliberately chosen to represent different microenvironments, from high-occupancy teaching spaces with mechanical ventilation to quiet study halls where students spend extended hours. Outdoor sensors were placed near Phayathai and Rama IV Roads, two of Bangkok&#8217;s busiest traffic arteries, to capture the pollution load generated by vehicles and campus activity. Each sensor recorded data at ten-minute intervals, producing an enormous dataset spanning both the dry and rainy seasons across three full annual cycles.</p>
<p>The instrumentation itself is a case study in modern environmental monitoring. The team used Plantower PMS5003 G5 sensors, compact laser-scattering devices that count particles as small as 0.3 micrometers. Before trusting the data, the researchers calibrated the sensors against reference-grade instruments: a U.S. EPA Federal Equivalent Method monitor for PM2.5 and a research-grade TSI DustTrak for PM10. The calibration results were impressive for PM2.5, with a coefficient of determination of 0.921 and a root mean square error of just 1.83 micrograms per cubic meter, though the sensors slightly underestimated concentrations. Performance for PM10 was more moderate, with an R-squared of 0.712, reflecting the well-known difficulty optical sensors face when estimating coarse particle mass, which is more sensitive to particle shape, density, and humidity-driven swelling.</p>
<p>The headline finding concerns seasonality. Monthly mean PM2.5 concentrations ranged from 0.8 to 20.8 micrograms per cubic meter indoors and 0.8 to 44.3 micrograms per cubic meter outdoors, with PM10 reaching up to 40.0 and 51.9 micrograms per cubic meter respectively. In every case, the dry season months from December to February produced the highest readings, a pattern the researchers attribute to a lower planetary boundary layer, regional biomass burning, transboundary pollution transport, and stagnant weather conditions during haze episodes. During those dry-season months, daily PM2.5 concentrations exceeded the World Health Organization&#8217;s 24-hour guideline of 15 micrograms per cubic meter in nearly every monitored building, both indoors and out. The only exception was the indoor air of the Central Library, whose filtration apparently kept fine particles at bay even as the city outside choked.</p>
<p>That library result points to the study&#8217;s most intriguing thread: the indoor-to-outdoor ratio, a simple but powerful metric that reveals whether a building&#8217;s air is dominated by outdoor infiltration or by sources within. An I/O ratio below one suggests outdoor air is the main driver, while values above one signal significant indoor generation or pollutant accumulation. The ratios varied wildly across buildings and years. The School of Agricultural Resources posted a mean ratio of 1.79 in 2023, with monthly values exceeding 2.0 during the mid-year months, hinting at occupant activities, resuspended dust, or insufficient ventilation. The Central Library, by contrast, achieved remarkably low ratios of 0.06 in 2022 and 0.29 in 2023, evidence of effective exclusion of outdoor particles, before jumping to 1.46 in 2024, possibly reflecting changes in ventilation operation or occupancy. Chamchuri 10 stayed below unity for three years, then surged to a mean of 1.55 in 2025. These swings demonstrate that building design, ventilation strategy, and human behavior can matter as much as the pollution outside.</p>
<p>Correlation analysis added another layer of nuance. Both indoor and outdoor particulate concentrations showed negative correlations with relative humidity and temperature, suggesting that meteorological factors did not directly drive pollution levels in this tropical setting. This finding contrasts with studies from temperate climates, where temperature differences drive the stack effect and window-opening behavior strongly modulates indoor air. In Bangkok&#8217;s perpetually warm and humid environment, where relative humidity exceeds 70 percent year-round, the seasonal signal appears dominated instead by regional pollution dynamics, particularly the agricultural burning that sweeps smoke across Southeast Asia each dry season.</p>
<p>Beyond measuring concentrations, the team translated their data into human terms by estimating exposure concentrations and potential inhaled doses for three age groups: children aged 6 to 11, adolescents aged 12 to 17, and adults. Using inhalation rates and exposure durations drawn from the U.S. EPA Exposure Factors Handbook, they calculated that adults accumulated the highest absolute inhaled doses, owing to their larger lung volumes and longer daily exposure times. But the researchers caution that a higher dose does not automatically mean higher risk. Children, whose lungs are still developing and who breathe more air per unit of body weight, may suffer disproportionately greater health consequences from the same concentration. Their developing respiratory and immune systems, combined with higher ventilation rates per kilogram of body mass, mean that identical exposure levels can translate into greater internal doses and more lasting harm.</p>
<p>The air quality index analysis offered a glimmer of hope amid the concern. Most monitoring days fell within the Very Good, Good, or Moderate categories of Thailand&#8217;s PM2.5-based AQI, and the trend from 2024 to 2025 improved compared with 2022 and 2023, when dry-season readings pushed into the Unhealthy range. Daily PM2.5 concentrations exceeded Thai national standards on only 0.24 to 5.32 percent of monitoring days, while PM10 exceeded standards on 1.70 to 14.1 percent of days. Short pollution episodes still occurred, however, and the study&#8217;s authors emphasize that these transient spikes can meaningfully raise exposure during exactly the periods when people are least prepared for them.</p>
<p>The practical implications extend well beyond the campus gates. Because indoor PM concentrations tracked outdoor levels at several sites, the researchers argue that building managers should factor outdoor conditions into ventilation decisions, ramping up filtration or deploying portable air cleaners during haze episodes rather than simply drawing in more outside air. At the policy level, they call for stricter vehicle emission standards, noting that Thailand&#8217;s adoption of EURO 5 and EURO 6 rules has been delayed, alongside better public transportation, stronger industrial regulation, and subsidies for HEPA filtration in schools and public buildings. The study explicitly ties these measures to United Nations Sustainable Development Goals on health, education, sustainable cities, and climate action, since the same combustion sources that produce PM2.5 also emit greenhouse gases.</p>
<p>The authors are careful to acknowledge the limits of their work. The measurements come from a single campus and cannot be generalized to all of Bangkok&#8217;s buildings, and the team did not analyze particle chemistry, monitor indoor activities like cooking or smoking, or measure air exchange rates directly, meaning the I/O ratios indicate relative relationships rather than true infiltration factors. The exposure estimates rely on generalized scenarios rather than individual time-activity data, and a sensitivity analysis confirmed that a 20 percent change in assumed inhalation rate or exposure duration shifts the calculated dose by exactly 20 percent. Still, as one of the longest continuous paired indoor-outdoor PM records in a tropical educational setting, the study delivers a clear message: in a megacity choking through its haze season, the air inside your building is only as clean as the walls, filters, and ventilation choices that separate it from the street.</p>
<p><strong>Subject of Research:</strong> Long-term indoor and outdoor PM2.5 and PM10 exposure assessment in university buildings in Bangkok, Thailand</p>
<p><strong>Article Title:</strong> Indoor and outdoor PM 2.5 and PM 10 exposure assessment in university buildings: A campus-based case study in Bangkok, Thailand</p>
<p><strong>Article References:</strong> Ahmad, M., Panyametheekul, S., Thaveevong, P., Ngamsritrakul, T., Bennett, C., Khan, M. T., &amp; Zhang, Y. (2026). Indoor and outdoor PM2.5 and PM10 exposure assessment in university buildings: A campus-based case study in Bangkok, Thailand. <em>Case Studies in Chemical and Environmental Engineering, 14</em>, Article 101491. <a href="https://doi.org/10.1016/j.cscee.2026.101491" rel="noopener noreferrer">https://doi.org/10.1016/j.cscee.2026.101491</a></p>
<p><strong>Image Credits:</strong> AI Generated</p>
<p><strong>DOI:</strong> <a href="https://doi.org/10.1016/j.cscee.2026.101491" rel="noopener noreferrer">10.1016/j.cscee.2026.101491</a></p>
<p><strong>Keywords:</strong> PM2.5, PM10, indoor air quality, Bangkok, air quality index, particulate matter, haze, exposure assessment, inhaled dose, university buildings, tropical megacity, WHO air quality guidelines</p>
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