Rice U. system selectively sequesters toxins from water

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Credit: Jeff Fitlow/Rice University

HOUSTON – (Aug. 6, 2018) – Rice University scientists are developing technology to remove contaminants from water – but only as many as necessary.

The Rice lab of engineer Qilin Li is building a treatment system that can be tuned to selectively pull toxins from drinking water and wastewater from factories, sewage systems and oil and gas wells. The researchers said their technology will cut costs and save energy compared to conventional systems.

"Traditional methods to remove everything, such as reverse osmosis, are expensive and energy intensive," said Li, the lead scientist and co-author of a study about the new technology in the American Chemical Society journal Environmental Science & Technology. "If we figure out a way to just fish out these minor components, we can save a lot of energy."

The heart of Rice's system is a set of novel composite electrodes that enable capacitive deionization. The charged, porous electrodes selectively pull target ions from fluids passing through the maze-like system. When the pores get filled with toxins, the electrodes can be cleaned, restored to their original capacity and reused.

"This is part of a broad scope of research to figure out ways to selectively remove ionic contaminants," said Li, a professor of civil and environmental engineering and of materials science and nanoengineering. "There are a lot of ions in water. Not everything is toxic. For example, sodium chloride (salt) is perfectly benign. We don't have to remove it unless the concentration gets too high.

"For many applications, we can leave non-hazardous ions behind, but there are certain ions that we need to remove," she said. "For example, in some drinking water wells, there's arsenic. In our drinking water pipes, there could be lead or copper. And in industrial applications, there are calcium and sulfate ions that form scale, a buildup of mineral deposits that foul and clog pipes."

The proof-of-principal system developed by Li's team removed sulfate ions, a scale-forming mineral that can give water a bitter taste and act as a laxative. The system's electrodes were coated with activated carbon, which was in turn coated by a thin film of tiny resin particles held together by quaternized polyvinyl alcohol. When sulfate-contaminated water flowed through a channel between the charged electrodes, sulfate ions were attracted by the electrodes, passed through the resin coating and stuck to the carbon.

Tests in the Rice lab showed the positively charged coating on the cathode preferentially captured sulfate ions over salt at a ratio of more than 20 to 1.

The electrodes retained their properties over 50 cycles. "But in fact, in the lab, we've run the system for several hundred cycles and I don't see any breaking or peeling of the material," said Kuichang Zuo, lead author of the paper and a postdoctoral researcher in Li's lab. "It's very robust."

Li said the system is intended to work with current commercial water-treatment systems. "The true merit of this work is not that we were able to selectively remove sulfate, because there are many other contaminants that are perhaps more important," she said. "The merit is that we developed a technology platform that we can use to target other contaminants as well by varying the composition of the electrode coating."

 <p>The Rice team is developing coatings for other contaminants and working with labs at the University of Texas at El Paso and Arizona State University on large-scale test systems. Zuo said it should also be possible to scale systems down for in-home water purification.   

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Rice graduate students Jun Kim and Amit Jain are co-lead authors of the paper. Co-authors include Tianxiao Wang, a Rice graduate student; Rafael Verduzco, associate professor of chemical and biomolecular engineering and of materials science and nanoengineering; and Mingce Long, an associate professor at China's Shanghai Jiao Tong University.

The research was supported by the Rice-based, National Science Foundation-backed Center for Nanotechnology-Enabled Water Treatment, the Welch Foundation and the Shanghai Municipal International Cooperation Foundation.

Read the abstract at https://pubs.acs.org/doi/10.1021/acs.est.8b01868.

This news release can be found online at http://news.rice.edu/2018/08/06/rice-u-system-selectively-sequesters-toxins-from-water/

Follow Rice News and Media Relations via Twitter @RiceUNews.

Related materials:

Qilin Li Research Group: http://qilinli.rice.edu

Verduzco Laboratory: http://verduzcolab.blogs.rice.edu

Center for Nanotechnology-Enabled Water Treatment: http://www.newtcenter.org

Rice Department of Civil and Environmental Engineering: https://ceve.rice.edu

Rice Department of Materials Science and NanoEngineering: https://msne.rice.edu

Rice Department of Chemical and Biomolecular Engineering: https://chbe.rice.edu

Images for download:

http://news.rice.edu/files/2018/08/0806_SULFATE-1-WEB-290slvm.jpg

Rice University's new platform technology can selectively filter contaminants from wastewater, drinking water and industrial fluids. In tests, an engineered coating of resin, polymer and activated carbon removed and trapped harmful sulfate ions, and other coatings can be used in the same platform to target other contaminants. (Credit: Illustration by Kuichang Zuo/Rice University)

 <p>http://news.rice.edu/files/2018/08/0806_SULFATE-2-WEB-2k8wyde.jpg  

In Rice University's new water-treatment platform, electrode coatings can be swapped out to allow the device to selectively remove a range of contaminants from wastewater, drinking water and industrial fluids. In tests, an engineered coating of resin, polymer and activated carbon removed and trapped harmful sulfate ions and allow most common salt ions to pass by. (Credit: Illustration by Kuichang Zuo/Rice University)

http://news.rice.edu/files/2018/08/0806_SULFATE-3-WEB-2hajrg6.jpg

Rice University researchers are developing ionic water-treatment technology that saves money and energy by selectively removing only hazardous contaminants and ignoring those that are harmless. From left: Kuichang Zuo, Qilin Li, Amit Jain and Rafael Verduzco. (Credit: Jeff Fitlow/Rice University)

http://news.rice.edu/files/2018/08/0806_SULFATE-4-WEB-1pfygaf.jpg

<p>Contaminants can be removed from fluids that traverse a maze-like path between electrodes in a technology developed by Rice University engineers. The photo shows Rice postdoctoral researcher Kuichang Zuo placing a separator that channels water through the system. (Credit: Jeff Fitlow/Rice University)</p>    <p>http://news.rice.edu/files/2018/08/0806_SULFATE-5-WEB-1utuam1.jpg</p>    <p>Rice University postdoctoral researcher Kuichang Zuo holds an assembled test unit of the lab's ionic water-treatment technology, which selectively removes hazardous contaminants and ignores those that are harmless. (Credit: Jeff Fitlow/Rice University)</p>    <p>Located on a 300-acre forested campus in Houston, Rice University is consistently ranked among the nation's top 20 universities by U.S. News &amp; World Report. Rice has highly respected schools of Architecture, Business, Continuing Studies, Engineering, Humanities, Music, Natural Sciences and Social Sciences and is home to the Baker Institute for Public Policy. With 3,970 undergraduates and 2,934 graduate students, Rice's undergraduate student-to-faculty ratio is just under 6-to-1. Its residential college system builds close-knit communities and lifelong friendships, just one reason why Rice is ranked No. 1 for quality of life and for lots of race/class interaction and No. 2 for happiest students by the Princeton Review. Rice is also rated as a best value among private universities by Kiplinger's Personal Finance. To read &quot;What they're saying about Rice,&quot; go to http://tinyurl.com/RiceUniversityoverview.  </p>                               <p><strong>Media Contact</strong></p>    <p>David Ruth  <br />713-348-6327  <br />[email protected]  

Mike Williams
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http://dx.doi.org/10.1021/acs.est.8b01868

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