An innovation that opens horizons for greenhouse gases’ remote monitoring
Fourier-transform infrared (FTIR) spectrometers, among the most frequently used research tools to identify and analyze chemicals, are too large to be used in the field to detect compounds.
Several attempts have been made to develop miniaturized FTIR spectrometers for integration into drones to monitor greenhouse gases remotely, for example, or for integration into smartphones and other devices. However, current miniaturized devices are costly to produce and therefore cannot be widely used.
Scientists at the University of Campinas's Device Research Laboratory (LPD-UNICAMP) in Brazil, collaborating with colleagues at the University of California San Diego in the United States, have overcome these constraints by developing an FTIR spectrometer based on silicon photonics, the technology currently used to produce chips for computers, smartphones and other electronic devices.
Resulting from Mário César Mendes Machado de Souza's PhD research and a research internship abroad, supported by scholarships from the São Paulo Research Foundation – FAPESP and supervised by Professor Newton Frateschi, the new spectrometer is described in an article published in Nature Communications. Souza is the article's lead author and thought up the project.
"Silicon photonics offers a platform for the fabrication of affordable high-performance miniaturized spectrometers," he said.
According to Souza, FTIR spectroscopy identifies chemicals using an infrared light source to measure absorption. A sample is exposed to different wavelengths of infrared light, and the spectrometer measures which wavelengths are absorbed. The computer takes these raw absorption data and conducts a mathematical process known as the Fourier transform to generate an absorbance pattern or spectrum, which is compared to a library of spectra for chemical compounds to find a match.
Various projects have appeared in recent years to develop an FTIR spectrometer based on integrated photonics, which uses light especially in the infrared spectrum, but progress had so far been scant owing to several technical challenges, Souza explained.
One of these challenges is the highly dispersive profile of silicon waveguides, meaning that each wavelength travels at a different speed in this material and hence has a different refractive index.
The refractive indices of optical waveguides in silicon can be "tuned" by means of the thermo-optical effect, which involves passing a current over the waveguide in order to heat it. Because the device has to be operated at high temperatures in order to achieve high resolution, this technique becomes non-linear in the sense that changes in temperature correlate with disproportionate changes in the refractive index.
"In practice, what happens when a thermo-optical effect is applied to a silicon-based infrared spectrometer with integrated photonics is that the Fourier transform mathematical operations used to convert the radiation spectrum data collected produce completely wrong results," Souza explained.
The researchers succeeded in overcoming these challenges by creating a laser calibration method to quantify and correct the distortions caused by silicon waveguide dispersion and non-linearity. As a proof of concept, they developed a 1 mm² FTIR spectrometer chip based on standard silicon photonics fabrication procedures.
The chip was tested in the laboratory, producing a broadband spectrum with a resolution of 0.38 terahertz (THz), which is comparable with the resolution of commercially available portable spectrometers that operate in the same wavelength range, according to the researchers.
"The device we developed is far from optimized but still achieves resolutions comparable with those of the portable free-space optics-based spectrometers available in the market today," Souza said.
The researchers now plan to engineer a device that is totally functional and integrated with photodetectors, light sources and optical fibers.
"Our goal is to integrate the light source and the spectrometer's detector into the same platform," Souza said.
About São Paulo Research Foundation (FAPESP)
The São Paulo Research Foundation (FAPESP) is a public institution with the mission of supporting scientific research in all fields of knowledge by awarding scholarships, fellowships and grants to investigators linked with higher education and research institutions in the State of São Paulo, Brazil. FAPESP is aware that the very best research can only be done by working with the best researchers internationally. Therefore, it has established partnerships with funding agencies, higher education, private companies, and research organizations in other countries known for the quality of their research and has been encouraging scientists funded by its grants to further develop their international collaboration. For more information: http://www.fapesp.br/en.
Joao Carlos da Silva
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